Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Catalysis and photocatalysis by metal organic frameworks

A Dhakshinamoorthy, Z Li, H Garcia - Chemical Society Reviews, 2018 - pubs.rsc.org
Metal organic frameworks (MOFs) are a class of porous crystalline materials that feature a
series of unique properties, such as large surface area and porosity, high content of …

Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis

Q Yang, Q Xu, HL Jiang - Chemical Society Reviews, 2017 - pubs.rsc.org
Metal–organic frameworks (MOFs), established as a relatively new class of crystalline
porous materials with high surface area, structural diversity, and tailorability, attract …

Development of MOF-derived carbon-based nanomaterials for efficient catalysis

K Shen, X Chen, J Chen, Y Li - Acs Catalysis, 2016 - ACS Publications
Carbon-based nanomaterials have been widely used as catalysts or catalyst supports in the
chemical industry or for energy or environmental applications due to their fascinating …

Application of metal and metal oxide nanoparticles@ MOFs

P Falcaro, R Ricco, A Yazdi, I Imaz, S Furukawa… - Coordination Chemistry …, 2016 - Elsevier
Abstract Composites based on Metal-Organic Frameworks (MOFs) are an emerging class of
porous materials that have been shown to possess unique functional properties …

Formation and stabilization of colloidal ultra-small palladium nanoparticles on diamine-modified Cr-MIL-101: Synergic boost to hydrogen production from formic acid

H Alamgholiloo, S Rostamnia, A Hassankhani… - Journal of colloid and …, 2020 - Elsevier
Ultra-small nano-sized palladium particles were successfully stabilized within the pores of
diamine groups grafted open metal site metal-organic frameworks of Cr-MIL-101; …

Copper-free Sonogashira cross-coupling reactions: an overview

F Mohajer, MM Heravi, V Zadsirjan… - RSC advances, 2021 - pubs.rsc.org
The Sonogashira reaction is a cross-coupling reaction of a vinyl or aryl halide with a terminal
alkyne to form a C–C bond. In its original form, the Sonogashira reaction is performed with a …

Organized aggregation makes insoluble perylene diimide efficient for the reduction of aryl halides via consecutive visible light-induced electron-transfer processes

L Zeng, T Liu, C He, D Shi, F Zhang… - Journal of the American …, 2016 - ACS Publications
The consecutive photo-induced electron-transfer (conPET) process found with perylene
diimide (PDI) overcomes the limitation of visible-light photocatalysis and sheds light on …

Chromium terephthalate metal–organic framework MIL-101: synthesis, functionalization, and applications for adsorption and catalysis

S Bhattacharjee, C Chen, WS Ahn - RSC advances, 2014 - pubs.rsc.org
The chromium terephthalate metal–organic framework, MIL-101 (MIL, Matérial Institut
Lavoisier), is comprised of trimeric chromium (III) octahedral clusters interconnected by 1, 4 …

Metal organic frameworks as robust host of palladium nanoparticles in heterogeneous catalysis: synthesis, application, and prospect

S Luo, Z Zeng, G Zeng, Z Liu, R Xiao… - … applied materials & …, 2019 - ACS Publications
Metal organic frameworks (MOFs) are one set of the most excellent supports for Pd
nanoparticles (NPs). MOFs as the host mainly have the following advantages:(i) they provide …