Formation and stabilization of nanosized Pd particles in catalytic systems: Ionic nitrogen compounds as catalytic promoters and stabilizers of nanoparticles
VM Chernyshev, OV Khazipov, DB Eremin… - Coordination Chemistry …, 2021 - Elsevier
Actual palladium catalysts in synthetic transformations in reaction mixtures are usually
represented by dynamic catalytic systems that contain various interconvertible forms of metal …
represented by dynamic catalytic systems that contain various interconvertible forms of metal …
Heterogenization of Pd (II) complexes as catalysts for the Suzuki-Miyaura reaction
J De Tovar, F Rataboul, L Djakovitch - Applied Catalysis A: General, 2021 - Elsevier
This review highlights the potential application and understanding of Pd (II) complexes
anchoring onto different supports as catalytic systems for the Suzuki-Miyaura reaction. The …
anchoring onto different supports as catalytic systems for the Suzuki-Miyaura reaction. The …
The Fast Formation of a Highly Active Homogeneous Catalytic System upon the Soft Leaching of Pd Species from a Heterogeneous Pd/C Precursor
AS Galushko, VV Ilyushenkova, JV Burykina… - Inorganics, 2023 - mdpi.com
Understanding the interface between soluble metal complexes and supported metal
particles is important in order to reveal reaction mechanisms in a new generation of highly …
particles is important in order to reveal reaction mechanisms in a new generation of highly …
From the grafting of NHC-based Pd (II) complexes onto TiO2 to the in situ generation of Mott-Schottky heterojunctions: The boosting effect in the Suzuki-Miyaura …
J De Tovar, F Rataboul, L Djakovitch - Journal of Catalysis, 2021 - Elsevier
The assumption that the real active species involved in the Suzuki-Miyaura reaction are
homogeneous, heterogeneous or both is often proposed. However a lack of characterization …
homogeneous, heterogeneous or both is often proposed. However a lack of characterization …
Water-soluble platinum nanoparticles stabilized by sulfonated N-heterocyclic carbenes: influence of the synthetic approach
The synthesis of metal nanoparticles (NPs) under controlled conditions in water remains a
challenge in nanochemistry. Two different approaches to obtain platinum NPs, which involve …
challenge in nanochemistry. Two different approaches to obtain platinum NPs, which involve …
Insights into the Suzuki‐Miyaura Reaction Catalyzed by Novel Pd− Carbene Complexes. Are Palladium− Tetra‐carbene Entities the Key Active Species?
J De Tovar, F Rataboul, L Djakovitch - ChemCatChem, 2020 - Wiley Online Library
The assumption that the real active species involved in the Suzuki‐Miyaura reaction are
homogeneous, heterogeneous or both is often proposed. However a lack in the …
homogeneous, heterogeneous or both is often proposed. However a lack in the …
Hydrodehalogenation of aryl halides by the mixture of palladium (II) and a newly synthesized chiral macrocyclic bis (N-heterocyclic carbene) ligand
X Xie, F Zhang, H Qin, X Lu, B Zhang, Q Sun - Inorganic Chemistry …, 2023 - Elsevier
A novel macrocyclic bis (N-heterocyclic carbene) precursor was designed and prepared,
which manifested high catalytic efficiency when combining Pd (OAc) 2 in …
which manifested high catalytic efficiency when combining Pd (OAc) 2 in …
Palladium nanoparticles supported on nitrogen doped porous carbon material derived from cyclodextrin, glucose and melamine based polymer: promising catalysts …
Melamine based polymer (MT) was prepared and then reacted with a mixture of glucose
(Glu) and β-cyclodextrin (CD) under hydrothermal conditions to afford, MT/Glu-CD. Then, the …
(Glu) and β-cyclodextrin (CD) under hydrothermal conditions to afford, MT/Glu-CD. Then, the …
N-Heterocyclic Carbene Modified Metal Nanocatalysts
P Lara, A Suárez - 2024 - Springer
The scientific community has widely studied the synthesis of metal nanoparticles (MNPs)
and their applications in a plethora of catalytic transformations for the last 25 years. In these …
and their applications in a plethora of catalytic transformations for the last 25 years. In these …
Tetraethylammonium (acetonitrile) trichloridopalladate (II)
AJ Oberley, LR Kadel, NK Senaratne, DM Eichhorn - IUCrData, 2018 - journals.iucr.org
A new square-planar palladium complex salt,(C8H20N)[PdCl3 (C2H3N)], has been formed
with one of the Cl atoms in tetrachloridopalladate (II) replaced by an acetonitrile coordinated …
with one of the Cl atoms in tetrachloridopalladate (II) replaced by an acetonitrile coordinated …