Photoinitiated thermoset polymerization through controlled release of metathesis catalysts encapsulated in poly (phthalaldehyde)

O Davydovich, J Lewis, M Romero, J Deitz… - Polymer …, 2025 - pubs.rsc.org
Photoinitiated polymerization enables spatiotemporal control of reaction conditions and can
thereby generate materials with high complexity while consuming minimal energy. Where …

Volumetric Additive Manufacturing of Dicyclopentadiene by Solid‐State Photopolymerization

MM Hausladen, E Baca, KA Nogales… - Advanced …, 2024 - Wiley Online Library
Polymerization in the solid state is generally infeasible due to restrictions on mobility.
However, in this work, the solid‐state photopolymerization of crystalline dicyclopentadiene is …

Intriguing combinations of p-cymene, chloride ion, phosphines, and amines in ruthenium metal centers: Which ligand decoordinates for ROMP?

RBG Caetano, PHO Santiago, JA Ellena… - Molecular …, 2024 - Elsevier
Cationic complexes of type [RuCl (Cym)(PR 3)(NH 2 R)] PF 6 were synthesized from
reactions of the precursors [RuCl 2 (Cym)(PPh 3)](1) and [RuCl 2 (Cym)(P (tol 3)](2) with NH …