Polyoxometalates (POMs) as inorganic polyanionic clusters with abundant structural
fashions at the nanometer level display diverse applications in aspects of chemistry …

Large water-soluble anions with chaotropic character display surprisingly strong
supramolecular interactions in water, for example, with macrocyclic receptors, polymers …

This review is intended to provide an up-to-date and comprehensive description of recent
advances since the mid-2010s in the elaboration and the involvement of polyoxometalates …

Polyoxometalates (POMs) are known antitumoral, antibacterial, antiviral, and anticancer
agents and considered as next‐generation metallodrugs. Herein, a new biological …

In aqueous solution, low-charged polyoxometalates (POMs) exhibit remarkable self-
assembly properties with nonionic organic matter that have been recently used to develop …

The rational development of an anion templation strategy for the construction of macrocycles
has been historically limited to small anions, but large polyoxoanions can offer unmatched …

Natural cyclodextrin (CD) macrocycles are known to form diverse inclusion complexes with a
wide variety of organic molecules, but recent work has revealed that inorganic clusters also …

Calixarenes are among the most useful and versatile macrocycles in supramolecular
chemistry. The one thing that has not changed in the 80 years since their discovery, despite …

Cup‐shaped molecules are of great interest due to their appealing architectures and
properties. Compared with widely studied calixarenes, polyoxometalate‐based cup‐shaped …

The construction of hierarchically nanoporous composite for high-performance catalytic
application is still challenging. In this work, a series of host-in-host ionic porous materials are …