Tris (pentafluorophenyl) borane catalyzed C–C and C–heteroatom bond formation
A series of boron based Lewis acids have been reported to date, but among them, tris
(pentafluorophenyl) borane (BCF) has gained the most significant attention in the synthetic …
(pentafluorophenyl) borane (BCF) has gained the most significant attention in the synthetic …
The use of the Thiol-Ene addition click reaction in the chemistry of organosilicon compounds: an alternative or a supplement to the classical hydrosilylation?
I Krizhanovskiy, M Temnikov, Y Kononevich… - Polymers, 2022 - mdpi.com
This review presents the main achievements in the use of the thiol-ene reaction in the
chemistry of silicones. Works are considered, starting from monomers and ending with …
chemistry of silicones. Works are considered, starting from monomers and ending with …
Silicone‐based polymer blends: Enhancing properties through compatibilization
Polymer blending is a cost‐effective way to control the properties of soft materials, but the
propensity for blends to macrophase separate motivates the development of efficient …
propensity for blends to macrophase separate motivates the development of efficient …
Effects of Hydride Transfer Ring-Opening Reaction on B(C6F5)3 Catalyzed Polymerization of D4H Cyclosiloxane and Dialkoxysilanes toward Thermally Stable …
The Piers–Rubinsztajn (PR) reaction catalyzed by a metal-free B (C6F5) 3 catalyst was
reported as efficient in synthesizing novel polysiloxanes through polycondensation of …
reported as efficient in synthesizing novel polysiloxanes through polycondensation of …
Photocatalytic Metal‐Free Radical Hydrosilylation for Polymer Functionalization†
Z Huang, K Liu, M Liu, J Yun, J Dong… - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary Post‐modification of polymers offers a route to prepare
functionalized polymers through efficient chemical reactions, and hydrosilylation is one of …
functionalized polymers through efficient chemical reactions, and hydrosilylation is one of …
Tris (pentafluorophenyl) borane-catalyzed Hydride transfer reactions in Polysiloxane Chemistry—Piers–Rubinsztajn reaction and related processes
S Rubinsztajn, J Chojnowski, U Mizerska - Molecules, 2023 - mdpi.com
Tris (pentafluorophenyl) borane (TPFPB) is a unique Lewis acid that catalyzes the
condensation between hydrosilanes (Si-H) and alkoxysilanes (Si-OR), leading to the …
condensation between hydrosilanes (Si-H) and alkoxysilanes (Si-OR), leading to the …
Superior hydrophobicity of nano-SiO2 porous thermal insulating material treated by oil-in-water microemulsion
X Song, R Fu, H Liu, Z Huang, X Su, X Liu - Ceramics International, 2022 - Elsevier
Nano-SiO 2 porous thermal insulating material (TIM) has drawn tremendous research
interests due to its advantages of low density, high porosity and low thermal conductivity …
interests due to its advantages of low density, high porosity and low thermal conductivity …
Heterotelechelic Silicones: Facile Synthesis and Functionalization Using Silane-Based Initiators
The synthetic utility of heterotelechelic polydimethylsiloxane (PDMS) derivatives is limited
due to challenges in preparing materials with high chain-end fidelity. In this study, anionic …
due to challenges in preparing materials with high chain-end fidelity. In this study, anionic …
Preparation of room temperature vulcanized silicone rubber foam/SiO2 nanocomposite and its fatigue buffering performance
Y Tan, J Yao, H Zhu - Journal of Macromolecular Science, Part A, 2020 - Taylor & Francis
A series of silicone rubber foam (SF)/silicon dioxide (SiO2) nanocomposites were prepared
by room temperature vulcanization. The effects of SiO2 content on the crosslinking density …
by room temperature vulcanization. The effects of SiO2 content on the crosslinking density …
Metal-Free Synthesis of Cross-Linkable Poly (silyl ether) s Using Cyclosiloxanes
B (C6F5) 3 was reported as an efficient metal-free catalyst for synthesis of poly (silyl ether) s
through hydrosilylation polyaddition of disilanes with diketones at ambient conditions. In this …
through hydrosilylation polyaddition of disilanes with diketones at ambient conditions. In this …