Tris (pentafluorophenyl) borane catalyzed C–C and C–heteroatom bond formation

G Kumar, S Roy, I Chatterjee - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
A series of boron based Lewis acids have been reported to date, but among them, tris
(pentafluorophenyl) borane (BCF) has gained the most significant attention in the synthetic …

The use of the Thiol-Ene addition click reaction in the chemistry of organosilicon compounds: an alternative or a supplement to the classical hydrosilylation?

I Krizhanovskiy, M Temnikov, Y Kononevich… - Polymers, 2022 - mdpi.com
This review presents the main achievements in the use of the thiol-ene reaction in the
chemistry of silicones. Works are considered, starting from monomers and ending with …

Silicone‐based polymer blends: Enhancing properties through compatibilization

A Abdilla, CA D'Ambra, Z Geng, JJ Shin… - Journal of Polymer …, 2021 - Wiley Online Library
Polymer blending is a cost‐effective way to control the properties of soft materials, but the
propensity for blends to macrophase separate motivates the development of efficient …

Effects of Hydride Transfer Ring-Opening Reaction on B(C6F5)3 Catalyzed Polymerization of D4H Cyclosiloxane and Dialkoxysilanes toward Thermally Stable …

H Zhu, S Hiruta, A Demirci, S Kim, N Hoshino… - …, 2022 - ACS Publications
The Piers–Rubinsztajn (PR) reaction catalyzed by a metal-free B (C6F5) 3 catalyst was
reported as efficient in synthesizing novel polysiloxanes through polycondensation of …

Photocatalytic Metal‐Free Radical Hydrosilylation for Polymer Functionalization

Z Huang, K Liu, M Liu, J Yun, J Dong… - Chinese Journal of …, 2023 - Wiley Online Library
Comprehensive Summary Post‐modification of polymers offers a route to prepare
functionalized polymers through efficient chemical reactions, and hydrosilylation is one of …

Tris (pentafluorophenyl) borane-catalyzed Hydride transfer reactions in Polysiloxane Chemistry—Piers–Rubinsztajn reaction and related processes

S Rubinsztajn, J Chojnowski, U Mizerska - Molecules, 2023 - mdpi.com
Tris (pentafluorophenyl) borane (TPFPB) is a unique Lewis acid that catalyzes the
condensation between hydrosilanes (Si-H) and alkoxysilanes (Si-OR), leading to the …

Superior hydrophobicity of nano-SiO2 porous thermal insulating material treated by oil-in-water microemulsion

X Song, R Fu, H Liu, Z Huang, X Su, X Liu - Ceramics International, 2022 - Elsevier
Nano-SiO 2 porous thermal insulating material (TIM) has drawn tremendous research
interests due to its advantages of low density, high porosity and low thermal conductivity …

Heterotelechelic Silicones: Facile Synthesis and Functionalization Using Silane-Based Initiators

Y Okayama, T Eom, M Czuczola, A Abdilla… - …, 2023 - ACS Publications
The synthetic utility of heterotelechelic polydimethylsiloxane (PDMS) derivatives is limited
due to challenges in preparing materials with high chain-end fidelity. In this study, anionic …

Preparation of room temperature vulcanized silicone rubber foam/SiO2 nanocomposite and its fatigue buffering performance

Y Tan, J Yao, H Zhu - Journal of Macromolecular Science, Part A, 2020 - Taylor & Francis
A series of silicone rubber foam (SF)/silicon dioxide (SiO2) nanocomposites were prepared
by room temperature vulcanization. The effects of SiO2 content on the crosslinking density …

Metal-Free Synthesis of Cross-Linkable Poly (silyl ether) s Using Cyclosiloxanes

N Yoshida, K Yamamoto, H Zhu… - ACS Applied Polymer …, 2024 - ACS Publications
B (C6F5) 3 was reported as an efficient metal-free catalyst for synthesis of poly (silyl ether) s
through hydrosilylation polyaddition of disilanes with diketones at ambient conditions. In this …