Recent progress in dissociative electron attachment: from diatomics to biomolecules

II Fabrikant, S Eden, NJ Mason, J Fedor - Advances in atomic, molecular …, 2017 - Elsevier
Dissociative electron attachment (DEA) processes occur in many important applied contexts,
particularly gas discharges, plasmas, biological systems, and astrophysical environments. In …

Gas phase negative ion chemistry

T Oster, A Kühn, E Illenberger - … journal of mass spectrometry and ion …, 1989 - Elsevier
The formation and decomposition of negative molecular ions following low energy electron
capture is studied using electron attachment and electron transmission spectroscopy. An …

Temporary anion states of polyatomic hydrocarbons

KD Jordan, PD Burrow - Chemical Reviews, 1987 - ACS Publications
The experimental methods used to characterize mo-lecular anions differ substantially
depending on the stability of the species. The application of laser spec-troscopic methods …

Ab initio electronic structure of anions

J Simons, KD Jordan - Chemical Reviews, 1987 - ACS Publications
In characterizing anion states either experimentally or theoretically different techniques are
required for bound and temporary or metastable anions. Anions that lie energetically above …

Electron attachment and intramolecular electron transfer in unsaturated chloroderivatives

A Modelli - Physical Chemistry Chemical Physics, 2003 - pubs.rsc.org
The electron transmission (ET) and dissociative electron attachment (DEA) spectra of
chloroalkyl ethene and ethyne derivatives are reported. B3LYP/6-31G* calculations are …

Ab Initio Molecular Dynamics of Temporary Anions Using Complex Absorbing Potentials

JA Gyamfi, TC Jagau - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
Dissociative electron attachment, that is, the cleavage of chemical bonds induced by low-
energy electrons, is difficult to model with standard quantum-chemical methods because the …

Electron attachment by haloalkenes and halobenzenes

JK Olthoff, JA Tossell, JH Moore - The Journal of chemical physics, 1985 - pubs.aip.org
Electron transmission spectra and mass spectra of negative ions from dissociative electron
attachment have been obtained for four series of halogenated alkenes: vinyl halides …

Temporary negative ions in the chloromethanes CHCl2F and CCl2F2: Characterization of the σ* orbitals

PD Burrow, A Modelli, NS Chiu… - The Journal of Chemical …, 1982 - pubs.aip.org
In this work, electron transmission spectroscopy (ETS) 1 is employed to study low-lying
temporary anions in the chloromethanes. The resulting electron affinities (EA), within the …

Faster dissociation: measured rates and computed effects on barriers in aryl halide radical anions

N Takeda, PV Poliakov, AR Cook… - Journal of the American …, 2004 - ACS Publications
Carbon− halogen bond dissociation rates for a series of aryl halide radical anions (ArX-•: X=
Cl, Br) in NMP were measured at room temperature by pulse radiolysis with 10-11 s time …

Effects of coupling on dissociative-electron-attachment angular distributions in vinyl, allyl, and benzyl chloride and in chlorobenzene

P Nag, M Tarana, J Fedor - Physical Review A, 2021 - APS
We report on a velocity map imaging study of Cl− anions resulting from the dissociative
electron attachment to four unsaturated chlorohydrocarbons. In all four molecules, this …