C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

An unprecedented Pd‐catalyzed fluorinative bifunctionalization of aziridines and azetidines
was successfully developed via regioselective C− C and C− F bond cleavage of gem …

C–H bonds are ubiquitous in organic molecules. Homogenous gold-catalyzed direct
functionalization of unsaturated C–H bonds has emerged as a powerful method in our …

Transition-metal-catalyzed carbene insertion reactions of a nitrogen–hydrogen bond have
emerged as robust and versatile methods for the construction of C–N bonds. While …

Asymmetric insertion of an arylvinylcarbenoid into the C–H bond for direct enantioselective
C (sp2)-H functionalization of aniline derivatives catalyzed by a rhodium (I)-diene complex …

The ubiquity of C–H bonds presents an opportunity to efficiently elaborate and build
complexity in organic molecules. Methods for selective functionalization, however, must …

An asymmetric para‐C (sp2)− H bond functionalization of alkyl benzene derivatives was
successfully developed via cooperative catalysis of gold and chiral phosphoric acid (CPA) …

The C–H functionalization reaction of N-heterocycles with an unprotected N–H group is one
of the most step-economic strategies to introduce functional groups without the need for …

Para-selective C–H functionalization of free phenols by metal carbenoids is rather
challenging due to the generally more favorable competing O–H insertion. Herein, with the …