50th Anniversary Perspective: A Perspective on Polyelectrolyte Solutions
M Muthukumar - Macromolecules, 2017 - ACS Publications
From the beginning of life with the information-containing polymers until the present era of a
plethora of water-based materials in health care industry and biotechnology, polyelectrolytes …
plethora of water-based materials in health care industry and biotechnology, polyelectrolytes …
Equilibrium and kinetically trapped aggregates in polyelectrolyte–oppositely charged surfactant mixtures
The widespread of mixtures formed by polyelectrolytes and oppositely charged surfactants
in different industrial sectors requires a thorough understanding of the physicochemical …
in different industrial sectors requires a thorough understanding of the physicochemical …
Salt partitioning in complex coacervation of symmetric polyelectrolytes
We perform a general thermodynamic analysis for the salt partitioning behavior in the
coexisting phases for symmetric mixtures of polycation and polyanion solutions. We find that …
coexisting phases for symmetric mixtures of polycation and polyanion solutions. We find that …
[HTML][HTML] Electrostatic correlations and the polyelectrolyte self energy
We address the effects of chain connectivity on electrostaticfluctuations in polyelectrolyte
solutions using a field-theoretic, renormalizedGaussian fluctuation (RGF) theory. As in …
solutions using a field-theoretic, renormalizedGaussian fluctuation (RGF) theory. As in …
[HTML][HTML] A unified analytical theory of heteropolymers for sequence-specific phase behaviors of polyelectrolytes and polyampholytes
The physical chemistry of liquid-liquid phase separation (LLPS) of polymer solutions bears
directly on the assembly of biologically functional dropletlike bodies from proteins and …
directly on the assembly of biologically functional dropletlike bodies from proteins and …
Polyelectrolyte chain structure and solution phase behavior
Using a recently developed renormalized Gaussian fluctuation (RGF) field theory that self-
consistently accounts for the concentration-dependent coupling between chain structure and …
consistently accounts for the concentration-dependent coupling between chain structure and …
Salting-out and salting-in of polyelectrolyte solutions: A liquid-state theory study
We study the phase behavior of polyelectrolyte (PE) solutions with salt using a simple liquid-
state (LS) theory. This LS theory accounts for hard-core excluded volume repulsion by the …
state (LS) theory. This LS theory accounts for hard-core excluded volume repulsion by the …
Conformational Behavior of a Single Dipolar Chain under Stretching Force
TY Merzliakova, YD Gordievskaya… - Macromolecules, 2023 - ACS Publications
The stretching of a single dipolar chain by a tensile force acting on the chain end is studied
using molecular dynamics simulations and theoretical considerations. In both theory and …
using molecular dynamics simulations and theoretical considerations. In both theory and …
Explicit description of complexation between oppositely charged polyelectrolytes as an advantage of the random phase approximation over the scaling approach
AM Rumyantsev, II Potemkin - Physical Chemistry Chemical Physics, 2017 - pubs.rsc.org
A polyelectrolyte complex (PEC) of oppositely charged linear chains is considered within the
Random Phase Approximation (RPA). We study the salt-free case and use the continuous …
Random Phase Approximation (RPA). We study the salt-free case and use the continuous …
Interplay of polymer structure, solvent ordering, and charge fluctuations in polyelectrolyte solution thermodynamics
M Beckinghausen, AJ Spakowitz - Macromolecules, 2022 - ACS Publications
We develop a polymer field-theoretic model that incorporates explicit treatment of
semiflexibility and polar solvents, providing a framework to determine the impact of solvent …
semiflexibility and polar solvents, providing a framework to determine the impact of solvent …