Coordination-directed self-assembly of functional polynuclear lanthanide supramolecular architectures

XZ Li, CB Tian, QF Sun - Chemical Reviews, 2022 - ACS Publications
Lanthanide supramolecular chemistry is a fast growing and intriguing research field due to
the unique photophysical, magnetic, and coordination properties of lanthanide ions (LnIII) …

Recent advances in the structural design and regulation of lanthanide clusters: Formation and self-assembly mechanisms

YL Li, HL Wang, ZH Zhu, FP Liang, HH Zou - Coordination Chemistry …, 2023 - Elsevier
The design and synthesis of lanthanide clusters with novel topological connections and
desirable properties are attracting extensive attention. Researchers have obtained …

Molecular assemblies from linear-shaped Ln 4 clusters to Ln 8 clusters using different β-diketonates: disparate magnetocaloric effects and single-molecule magnet …

WM Wang, ZL Wu, JZ Cui - Dalton Transactions, 2021 - pubs.rsc.org
A series of tetranuclear lanthanide-based clusters [Ln4 (dbm) 6 (L) 2 (CH3OH) 4]· 2CH3OH
(Ln (III)= Gd (1), Dy (2), and Ho (3); H3L= 2-[(2-(hydroxyimino) propanehydrazide) methyl]-2 …

Modulating single-molecule magnet behaviour of phenoxo-O bridged lanthanide (III) dinuclear complexes by using different β-diketonate coligands

WM Wang, SY Wang, HX Zhang, HY Shen… - Inorganic Chemistry …, 2016 - pubs.rsc.org
Three dinuclear Dy (III) complexes,[Dy2 (tfa) 4L2](1),[Dy2 (TTA) 4L2](2) and [Dy2 (dbm) 4L2·
2CH3CN· 0.5 H2O](3)(tfa= trifluoroacetylacetonate, TTA= 2-thenoyltrifluoroacetone, dbm …

Suppression of zero-field quantum tunneling of magnetization by a fluorido bridge for a" very hard" 3d-4f single-molecule magnet

BK Ling, YQ Zhai, PB Jin, HF Ding, XF Zhang, Y Lv… - Matter, 2022 - cell.com
Single-molecule magnets (SMMs) have been proposed for ultra-high-density information
storage due to prolonged relaxation times below blocking temperature (TB). However, many …

'Windmill'-shaped Ln III4 (Ln III= Gd and Dy) clusters: magnetocaloric effect and single-molecule-magnet behavior

WM Wang, MJ Wang, SS Hao, QY Shen… - New Journal of …, 2020 - pubs.rsc.org
Two new tetranuclear lanthanide clusters with the formula [Ln4 (L) 4 (μ2-CH3O) 4]·
4CH3OH· xC2H5OH (LnIII= Gd (1) and Dy (2), H2L= N′-(4-diethylamino-2 …

A Family of Lanthanide Hydroxo Carboxylates with 1D Polymeric Topology and Ln4 Butterfly Core Exhibits Switchable Supramolecular Arrangement

D Grebenyuk, M Zobel, M Polentarutti, L Ungur… - Inorganic …, 2021 - ACS Publications
The unique family of coordination polymers [Ln4 (OH) 2 (piv) 10 (H2O) 2]∞ of 11
lanthanides (Ln= La–Er) has been prepared by a simple solution method based on …

3D Ln III-MOFs: slow magnetic relaxation and highly sensitive luminescence detection of Fe 3+ and ketones

F Zhao, XY Guo, ZP Dong, ZL Liu, YQ Wang - Dalton Transactions, 2018 - pubs.rsc.org
Five new 3D isostructural lanthanide metal organic frameworks (Ln-MOFs),[Ln (HL) 1.5
(H2O)(DMF)]· 2H2O (Ln= GdIII (1), SmIII (2), DyIII (3), EuIII (4) and TbIII (5), H3L= 5-(3′, 5 …

Slow magnetic relaxation and luminescence properties in β-diketonate lanthanide (iii) complexes. Preparation of Eu (iii) and Yb (iii) OLED devices

À Tubau, L Rodríguez, P Pander, L Weatherill… - Journal of Materials …, 2024 - pubs.rsc.org
The reaction of [Ln (btfa) 3 (H2O) 2](btfa−= 4, 4, 4-trifluoro-1-phenyl-1, 3-butanedionate) with
4, 4′-dinonyl-2, 2′-bipyridyl (4, 4′-dinonylbipy) in ethanol allows isolation of …

3D isomorphous lanthanide coordination polymers displaying magnetic refrigeration, slow magnetic relaxation and tunable proton conduction

SP Bera, A Mondal, S Roy, B Dey, A Santra… - Dalton …, 2018 - pubs.rsc.org
Four new isostructural lanthanide-based three-dimensional (3D) coordination polymers
(CPs),{[Ln4 (OH) 4 (L) 2 (H2O) 8]· 4.6 H2O· 1.4 CH3CN} n (Ln3+= Gd3+ (1), Dy3+ (2), Ho3+ …