Construction and application of base-stable MOFs: a critical review

K Wang, Y Li, LH Xie, X Li, JR Li - Chemical Society Reviews, 2022 - pubs.rsc.org
Metal–organic frameworks (MOFs) are a new class of porous crystalline materials
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …

Challenges to developing materials for the transport and storage of hydrogen

MD Allendorf, V Stavila, JL Snider, M Witman… - Nature Chemistry, 2022 - nature.com
Hydrogen has the highest gravimetric energy density of any energy carrier and produces
water as the only oxidation product, making it extremely attractive for both transportation and …

In situ synthesis of MOF‐74 family for high areal energy density of aqueous nickel–zinc batteries

T Chen, F Wang, S Cao, Y Bai, S Zheng… - Advanced …, 2022 - Wiley Online Library
Limited by single metal active sites and low electrical conductivity, designing nickel‐based
metal–organic framework (MOF) materials with high capacity and high energy density …

Porous materials for hydrogen storage

Z Chen, KO Kirlikovali, KB Idrees, MC Wasson… - Chem, 2022 - cell.com
The development of efficient storage materials for hydrogen is important for the viable
implementation of hydrogen-powered fuel-cell automobiles. In this review, we summarize …

Progress and potential of metal-organic frameworks (MOFs) for gas storage and separation: A review

T Jia, Y Gu, F Li - Journal of Environmental Chemical Engineering, 2022 - Elsevier
Gas storage and separation plays the most critically vital role in the utilization of energy
resources and the petrochemical industry in modern society. The development of industry …

Power of infrared and raman spectroscopies to characterize metal-organic frameworks and investigate their interaction with guest molecules

KI Hadjiivanov, DA Panayotov, MY Mihaylov… - Chemical …, 2020 - ACS Publications
The variety of functionalities and porous structures inherent to metal-organic frameworks
(MOFs) together with the facile tunability of their properties makes these materials suitable …

A reticular chemistry guide for the design of periodic solids

H Jiang, D Alezi, M Eddaoudi - Nature Reviews Materials, 2021 - nature.com
Reticular chemistry—the linking of well-defined molecular building blocks by strong bonds
into crystalline extended frameworks—has enabled the synthesis of diverse metal–organic …

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Porous aromatic frameworks (PAFs)

Y Tian, G Zhu - Chemical reviews, 2020 - ACS Publications
Porous aromatic frameworks (PAFs) represent an important category of porous solids. PAFs
possess rigid frameworks and exceptionally high surface areas, and, uniquely, they are …

Porous metal–organic frameworks for hydrogen storage

D Zhao, X Wang, L Yue, Y He, B Chen - Chemical Communications, 2022 - pubs.rsc.org
The high gravimetric energy density and environmental benefits place hydrogen as a
promising alternative to the widely used fossil fuels, which is however impeded by the lack of …