C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

Conspectus Over recent decades, N-sulfonylhydrazones have attracted significant attention
in academic and industrial contexts owing to their ease of preparation, versatile reactivity …

The construction of carbon–carbon bonds is a central tenet of modern synthetic chemistry.
Metal-catalyzed C–H functionalization can serve as a particularly powerful tool for achieving …

C H oxidation has a long history and an ongoing presence in research at the forefront of
chemistry and interrelated fields. As such, numerous highly useful articles and reviews have …

From its earliest observation as an unusual reaction only a half century ago, 1 the insertion
of a carbene into a carbonrhydrogen bond has attracted considerable interest because of its …

Synthetic manipulation of polymer substrates is one of the oldest and most reliable methods
to increase the functional diversity of soft materials. Modifying the chemical structure of …

Novel reactions that can selectively functionalize carbon–hydrogen bonds are of intense
interest to the chemical community because they offer new strategic approaches for …

The demand for more efficient ways to construct complex chemical structures from simple,
readily available precursors continues unabated. A very attractive way to meet this demand …

Seven kinds of sp3 α-C–H activation/C–C formation reactions of alcohols and ethers have
been reviewed in this tutorial review, from the viewpoint of both methodology and synthetic …

The usually employed term of Holy Grail in the search of efficient methods that convert
readily available sources such as hydrocarbons into value added products is yet completely …