Nitrogen fixation is considered one of the grand challenges of the 21st century for achieving
the ultimate vision of a green and sustainable future. It is crucial to develop and design …

This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Reduction of N2 by nitrogenases occurs at an organometallic iron cofactor that commonly
also contains either molybdenum or vanadium. The well-characterized resting state of the …

Numerous reports claim that quantum advantage, which should emerge as a direct
consequence of the advent of quantum computers, will herald a new era of chemical …

Late-transition-metal-based catalysts are widely used in N2 fixation reactions, but the
reactivity of late-transition-metal N2 complexes, besides iron N2 complexes, has remained …

Using a pyrazolate‐bridged dinucleating ligand that provides two proximate pincer‐type
PNN binding sites (“two‐in‐one pincer”), different synthetic routes have been developed …

The electrochemical reduction of nitrogen to produce ammonia using sustainable and
“green” materials and electricity has proven to be not only feasible, but promising. However …

Nitrogenases catalyse nitrogen fixation to ammonia on a multinuclear Fe‐Mo centre, but
their mechanism and particularly the order of proton and electron transfer processes that …

A compartmental ligand scaffold HL with two β-diketiminato binding sites spanned by a
pyrazolate bridge gave a series of dinuclear nickel (II) dihydride complexes M [LNi2 (H) 2] …

While the thermal activation of the dinitrogen molecule has been demonstrated in numerous
examples with a variety of transition metals and ligand frameworks, the use of light to induce …