Mechanochemical tools for polymer materials

Y Chen, G Mellot, D van Luijk, C Creton… - Chemical Society …, 2021 - pubs.rsc.org
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …

A review on self-healing polymers for soft robotics

S Terryn, J Langenbach, E Roels, J Brancart… - Materials Today, 2021 - Elsevier
The intrinsic compliance of soft robots provides safety, a natural adaptation to its
environment, allows to absorb shocks, and protects them against mechanical impacts …

A review on mechanochemistry: Approaching advanced energy materials with greener force

X Liu, Y Li, L Zeng, X Li, N Chen, S Bai, H He… - Advanced …, 2022 - Wiley Online Library
Mechanochemistry with solvent‐free and environmentally friendly characteristics is one of
the most promising alternatives to traditional liquid‐phase‐based reactions, demonstrating …

The many flavours of mechanochemistry and its plausible conceptual underpinnings

RT O'Neill, R Boulatov - Nature Reviews Chemistry, 2021 - nature.com
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …

Mechanochemistry as an emerging tool for molecular synthesis: what can it offer?

JL Howard, Q Cao, DL Browne - Chemical science, 2018 - pubs.rsc.org
Mechanochemistry is becoming more widespread as a technique for molecular synthesis
with new mechanochemical reactions being discovered at increasing frequency. Whilst …

Azobenzene as a photoswitchable mechanophore

Y Li, B Xue, J Yang, J Jiang, J Liu, Y Zhou, J Zhang… - Nature Chemistry, 2024 - nature.com
Azobenzene has been widely explored as a photoresponsive element in materials science.
Although some studies have investigated the force-induced isomerization of azobenzene …

Future‐oriented advanced diarylethene photoswitches: from molecular design to spontaneous assembly systems

HB Cheng, S Zhang, E Bai, X Cao, J Wang… - Advanced …, 2022 - Wiley Online Library
Diarylethene (DAE) photoswitch is a new and promising family of photochromic molecules
and has shown superior performance as a smart trigger in stimulus‐responsive materials …

Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer

H Hu, X Cheng, Z Ma, RP Sijbesma… - Journal of the American …, 2022 - ACS Publications
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …

Validation of the CoGEF method as a predictive tool for polymer mechanochemistry

IM Klein, CC Husic, DP Kovács… - Journal of the …, 2020 - ACS Publications
The development of force-responsive molecules called mechanophores is a central
component of the field of polymer mechanochemistry. Mechanophores enable the design …

Harnessing the power of force: development of mechanophores for molecular release

BA Versaw, T Zeng, X Hu, MJ Robb - Journal of the American …, 2021 - ACS Publications
Polymers that release small molecules in response to mechanical force are promising
materials for a variety of applications ranging from sensing and catalysis to targeted drug …