Water stability and adsorption in metal–organic frameworks

NC Burtch, H Jasuja, KS Walton - Chemical reviews, 2014 - ACS Publications
1. INTRODUCTION The ability to synthesize porous metal− organic frameworks (MOFs) with
prescribed structural features (Figure 1) has led to intense interest in the materials for …

Carbon dioxide capture in metal–organic frameworks

K Sumida, DL Rogow, JA Mason, TM McDonald… - Chemical …, 2012 - ACS Publications
The sharply rising level of atmospheric carbon dioxide resulting from anthropogenic
emissions is one of the greatest environmental concerns facing our civilization today. These …

Progress in adsorption-based CO 2 capture by metal–organic frameworks

J Liu, PK Thallapally, BP McGrail, DR Brown… - Chemical Society …, 2012 - pubs.rsc.org
Metal–organic frameworks (MOFs) have recently attracted intense research interest because
of their permanent porous structures, large surface areas, and potential applications as …

Challenges and opportunities for mixed-matrix membranes for gas separation

G Dong, H Li, V Chen - Journal of Materials Chemistry A, 2013 - pubs.rsc.org
Mixed-Matrix Membranes (MMMs) combining the benefits of both polymeric and inorganic
materials have become a focus for the next-generation gas separation membranes. In this …

Effect of water adsorption on retention of structure and surface area of metal–organic frameworks

PM Schoenecker, CG Carson, H Jasuja… - Industrial & …, 2012 - ACS Publications
This work presents an experimental investigation of water adsorption in metal–organic
frameworks (MOFs) at room temperature and up to 90% relative humidity. Structural …

Stability and hydrolyzation of metal organic frameworks with paddle-wheel SBUs upon hydration

K Tan, N Nijem, P Canepa, Q Gong, J Li… - Chemistry of …, 2012 - ACS Publications
Instability of most prototypical metal organic frameworks (MOFs) in the presence of moisture
is always a limitation for industrial scale development. In this work, we examine the …

Investigation of the MOF adsorbents and the gas adsorptive separation mechanisms

MF Ghazvini, M Vahedi, SN Nobar, F Sabouri - Journal of Environmental …, 2021 - Elsevier
Due to their high pore volume and high porosity, Metal-Organic Frameworks (MOFs),
containing one-, two-, and three-dimensional structures, have been developing at an …

Selective capture of carbon dioxide under humid conditions by hydrophobic chabazite‐type zeolitic imidazolate frameworks

NTT Nguyen, H Furukawa, F Gándara… - Angewandte Chemie …, 2014 - Wiley Online Library
Hydrophobic zeolitic imidazolate frameworks (ZIFs) with the chabazite (CHA) topology are
synthesized by incorporating two distinct imidazolate links. Zn (2‐mIm) 0.86 (bbIm) 1.14 (ZIF …

Hypercrosslinked organic polymer networks as potential adsorbents for pre-combustion CO 2 capture

CF Martín, E Stöckel, R Clowes, DJ Adams… - Journal of Materials …, 2011 - pubs.rsc.org
Hypercrosslinked polymers (HCPs) synthesized by copolymerisation of p-dichloroxylene (p-
DCX) and 4, 4′-bis (chloromethyl)-1, 1′-biphenyl (BCMBP) constitute a family of low …

Water interactions in metal organic frameworks

K Tan, N Nijem, Y Gao, S Zuluaga, J Li… - …, 2015 - pubs.rsc.org
Metal organic frameworks (MOFs) have a strong potential for gas adsorption and separation
such as H2 and CH4 storage, and CO2 capture. However, their instability in the presence of …