Chemistry with methane: concepts rather than recipes

H Schwarz - Angewandte Chemie International Edition, 2011 - Wiley Online Library
Four seemingly simple transformations related to the chemistry of methane will be
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …

How and why do cluster size, charge state, and ligands affect the course of metal‐mediated gas‐phase activation of methane?

H Schwarz - Israel Journal of Chemistry, 2014 - Wiley Online Library
Recent progress in the gas‐phase activation of methane is discussed. We demonstrate that
cluster size, charge state, and ligands crucially affect both the reactivity and selectivity of …

Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States 136

WJ Evans - Organometallics, 2016 - ACS Publications
A fundamental aspect of any element is the range of oxidation states accessible for useful
chemistry. This tutorial describes the recent expansion of the number of oxidation states …

Chemie mit Methan: Studieren geht über Probieren!

H Schwarz - Angewandte Chemie, 2011 - Wiley Online Library
Konzeptionelle Überlegungen zu und mechanistische Aspekte von vier scheinbar einfachen
chemischen Umsetzungen, die in der Chemie von Methan von Bedeutung sind, werden in …

Expanding the+ 2 oxidation state of the rare-earth metals, uranium, and thorium in molecular complexes

DH Woen, WJ Evans - Handbook on the Physics and Chemistry of Rare …, 2016 - Elsevier
The review describes recent developments in the low oxidation state chemistry of the rare-
earth elements since the publication in 2010 of Chapter 246 in this series on “The Molecular …

Reactions of U+ with H2, D2, and HD Studied by Guided Ion Beam Tandem Mass Spectrometry and Theory

WJ Zhang, M Demireva, JS Kim… - The Journal of …, 2021 - ACS Publications
The kinetic energy-dependent reactions of the atomic actinide uranium cation (U+) with H2,
D2, and HD were examined by guided ion beam tandem mass spectrometry. An average 0 …

Density Functional Theory Studies of UO22+ and NpO2+ Complexes with Carbamoylmethylphosphine Oxide Ligands

CZ Wang, JH Lan, YL Zhao, ZF Chai, YZ Wei… - Inorganic …, 2013 - ACS Publications
The UO22+ and NpO2+ extraction complexes with n-octyl (phenyl)-N, N-
diisobutylmethylcarbamoyl phosphine oxide (CMPO) and diphenyl-N, N …

Actinide (An= Th–Pu) dimetallocenes: promising candidates for metal–metal multiple bonds

CZ Wang, JK Gibson, JH Lan, QY Wu, YL Zhao… - Dalton …, 2015 - pubs.rsc.org
Synthesis of complexes with direct actinide–actinide (An–An) bonding is an experimental
'holy grail'in actinide chemistry. In this work, a series of actinide dimetallocenes An2Cp* 2 …

Theoretical studies on the complexation of Eu (III) and Am (III) with HDEHP: structure, bonding nature and stability

J Luo, C Wang, J Lan, Q Wu, Y Zhao, Z Chai… - Science China …, 2016 - Springer
Separation of trivalent lanthanides (Ln (III)) and actinides (An (III)) is a key issue in the
advanced spent nuclear fuel reprocessing. In the well-known trivalent actinide lanthanide …

Mass spectrometric and theoretical study on the formation of uranyl hydride from uranyl carboxylate

Z Xiong, X Chen, Y Gong - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Uranyl hydride in the form of HUO2Cl2− was prepared upon collision-induced dissociation
of (RCO2) UO2Cl2−(R= H, CH3CH2, CH3CH2CH2, CH3CHCH,(CH3) 2CH, C5H9, C6H11 …