The methodological developments in gold (I)-and gold (III)-catalyzed glycosylation reactions
are fully surveyed, which exploit the special alkynophilicity or the Lewis acidity of the gold …

Thioglycosides are among the most common glycosyl donors that find broad application in
the synthesis of glycans and glycoconjugates. However, the requirement for toxic and/or …

Carbohydrate chemistry has benefited a lot from the intrinsic reactivity of sulfoxide since it
was introduced in glycosylation reactions by Kahne in 1989. Since then, extensive studies …

Photocatalytic formation of glycosidic bonds employing stable and readily accessible O-
glycosyl derivatives of 2, 2, 6, 6-tetramethylpiperidin-1-ol is presented that employs an …

Glycans have been hot topics in recent years due to their exhibition of numerous biological
activities. However, the heterogeneity of their natural source and the complexity of their …

Sulfoxides have emerged as pivotal constituents in modern carbohydrate chemistry. As
anomeric leaving groups, sulfinyl moieties may occupy positions directly at the anomeric …

Gold catalysis has emerged as an important tool in the field of synthetic organic chemistry for
the selective functionalization of C–C multiple bonds. The research in India on gold catalysis …

A novel gold-catalyzed C-glycosylation has been developed to gain access to α,(Z)-selective
C-vinyl glycosides, starting from readily available glycals and propargylic carboxylate. This …

A novel glycosylation protocol has been established by using N-(glycosyloxy) acetamides as
glycosyl donors. The N-oxyacetamide leaving group in donors could be rapidly activated in …

An efficient and completely β-stereoselective glycosylation that did not rely on neighboring
group participation is described using 2–20 mol% FeCl 3/C as the catalyst and benzylated …