Since its early days, olefin metathesis has been in the focus of scientific discussions and
technology development. While heterogeneous olefin metathesis catalysts based on …

Conspectus Metal-bonded carbon atoms in metal–alkyl, metal–carbene/alkylidene, and
metal–carbyne/alkylidyne species often show significantly more deshielded isotropic …

The olefin metathesis activity of silica-supported molybdenum oxides depends strongly on
metal loading and preparation conditions, indicating that the nature and/or amounts of the …

A MoO x/SiO2 system is an effective catalyst for alkene metathesis; however, the mechanism
of the transformation of the surface metal oxide species into active alkylidene sites is not well …

Single-site supported organometallic catalysts bring together the favorable aspects of
homogeneous and heterogeneous catalysis while offering opportunities to investigate the …

Four new Mo (NAr)(CR1R2)(OSiPh3) 2 complexes (Ar= 2, 6-i-Pr2C6H3; CR1R2= CMe2,
CMeCH2Ph, CEtPh, or CHCH2Ph) were prepared through addition of CH2═ CR1R2 to a …

Despite the importance of the heterogeneous tungsten–oxo-based olefin metathesis catalyst
(WO3/SiO2) in industry, understanding of its initiation mechanism is still very limited. It has …

β, β′-Disubstituted tungstacyclopentane complexes have been prepared through addition
of propylene, 1-heptene, 1, 6-heptadiene, 1, 7-octadiene, or diallylaniline to unsubstituted …

Upon addition of 5–15% PhNMe2H+ X–(X= B (3, 5-(CF3) 2C6H3) 4 or B (C6F5) 4) to Mo
(NAr)(styrene)(OSiPh3) 2 (Ar= N-2, 6-i-Pr2C6H3) in C6D6 an equilibrium mixture of Mo …

The controllable selective oxidation of anilines to metastable and valuable products
mediated by a single catalyst represents a long-standing synthetic challenge due to the …