Multicomponent reactions and photo/electrochemistry join forces: atom economy meets energy efficiency
Visible-light photoredox catalysis has been regarded as an extremely powerful tool in
organic chemistry, bringing the spotlight back to radical processes. The versatility of …
organic chemistry, bringing the spotlight back to radical processes. The versatility of …
Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds
R Cannalire, S Pelliccia, L Sancineto… - Chemical Society …, 2021 - pubs.rsc.org
The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …
to speed up the identification of structure–activity relationships (SARs) and to optimize …
Synthetic methods driven by the photoactivity of electron donor–acceptor complexes
GEM Crisenza, D Mazzarella… - Journal of the American …, 2020 - ACS Publications
The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …
Bond-forming and-breaking reactions at sulfur (IV): sulfoxides, sulfonium salts, sulfur ylides, and sulfinate salts
D Kaiser, I Klose, R Oost, J Neuhaus… - Chemical …, 2019 - ACS Publications
Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …
development of novel chemical structures and architectures. Prominent among these …
A general organocatalytic system for electron donor–acceptor complex photoactivation and its use in radical processes
E de Pedro Beato, D Spinnato, W Zhou… - Journal of the …, 2021 - ACS Publications
We report herein a modular class of organic catalysts that, acting as donors, can readily form
photoactive electron donor–acceptor (EDA) complexes with a variety of radical precursors …
photoactive electron donor–acceptor (EDA) complexes with a variety of radical precursors …
Visible light-driven organic photochemical synthesis in China
Y Chen, LQ Lu, DG Yu, CJ Zhu, WJ Xiao - Science China Chemistry, 2019 - Springer
In recent years, visible light-driven organic photochemical synthesis has attracted wide
research interest from academic and industrial communities due to its features of green and …
research interest from academic and industrial communities due to its features of green and …
Recent advances in the application of Diels–Alder reactions involving o-quinodimethanes, aza-o-quinone methides and o-quinone methides in natural product total …
B Yang, S Gao - Chemical Society Reviews, 2018 - pubs.rsc.org
In recent decades, transient and highly reactive ortho-quinodimethanes (o-QDMs), ortho-
quinone methides (o-QMs) and aza-ortho-quinone methides (aza-o-QMs) have attracted …
quinone methides (o-QMs) and aza-ortho-quinone methides (aza-o-QMs) have attracted …
Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
C Chen, ZJ Wang, H Lu, Y Zhao, Z Shi - Nature Communications, 2021 - nature.com
Sulfonium salts bearing a positively charged sulfur atom with three organic substituents
have intrigued chemists for more than a century for their unusual structures and high …
have intrigued chemists for more than a century for their unusual structures and high …
Catalyst‐Free Deaminative Functionalizations of Primary Amines by Photoinduced Single‐Electron Transfer
The use of pyridinium‐activated primary amines as photoactive functional groups for
deaminative generation of alkyl radicals under catalyst‐free conditions is described. By …
deaminative generation of alkyl radicals under catalyst‐free conditions is described. By …
[HTML][HTML] Synthetic reactions driven by electron-donor–acceptor (EDA) complexes
Z Yang, Y Liu, K Cao, X Zhang… - Beilstein Journal of …, 2021 - beilstein-journals.org
The reversible, weak ground-state aggregate formed by dipole–dipole interactions between
an electron donor and an electron acceptor is referred to as an electron-donor–acceptor …
an electron donor and an electron acceptor is referred to as an electron-donor–acceptor …