[HTML][HTML] Microbial conversion of syngas to single cell protein: The role of carbon monoxide

Y Jiang, X Yang, D Zeng, Y Su, Y Zhang - Chemical Engineering Journal, 2022 - Elsevier
Syngas has been widely utilized as substrate in microbial processes to produce various high-
value products. Nevertheless, its applicability for single cell protein (SCP) production by …

Syngas Instead of Hydrogen Gas as a Reducing Agent─ A Strategy To Improve the Selectivity and Efficiency of Organometallic Catalysts

E Podyacheva, OI Afanasyev, VS Ostrovskii… - ACS catalysis, 2022 - ACS Publications
Catalytic reduction reactions play a major role in modern chemistry and are often based on
hydrogen gas as a reducing agent. However, the high reactivity of hydrogen is often …

A neutral crystalline imino-substituted silyl radical

FJ Kiefer, A Kostenko, R Holzner, S Inoue - Chemical Communications, 2024 - pubs.rsc.org
The neutral three-coordinated imino (silyl) silyl radical was isolated from the reaction of N-
heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully …

[HTML][HTML] Arene-osmium (II) complexes in homogeneous catalysis

P Crochet, V Cadierno - Inorganics, 2021 - mdpi.com
Although the application of arene-osmium (II) complexes in homogeneous catalysis has
been much less studied than that of their ruthenium analogues, different works have shown …

Easy Access to Versatile Catalytic Systems for C− H Activation and Reductive Amination Based on Tetrahydrofluorenyl Rhodium (III) Complexes

VB Kharitonov, SA Runikhina… - … A European Journal, 2021 - Wiley Online Library
On the basis of the 1, 2, 3, 4‐tetrahydrofluorenyl ligand, a simple approach was developed
to new effective rhodium catalysts for the construction of C− C and C− N bonds. The halide …

Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power

KO Biriukov, MM Vinogradov, OI Afanasyev… - Catalysis Science & …, 2021 - pubs.rsc.org
Herein, we present the first example of Os-catalyzed efficient reductive amination under
water–gas shift reaction conditions. The developed catalytic systems are formed in situ in …

Density Functional Theory Study on the Selective Reductive Amination of Aldehydes and Ketones over Their Reductions to Alcohols Using Sodium …

SJ Oliphant, RH Morris - ACS omega, 2022 - ACS Publications
Reductive amination is one of the most important methods to synthesize amines, having a
wide application in the pharmaceutical, fine chemicals, and materials industries. In general …

Theoretical investigation of mechanism and ligand effects on half-sandwich iridium complexes for direct reductive amination

J Wang, C Liu, L Cao, Y Xiong, J Ye, Z Liu, R Cheng - Molecular Catalysis, 2022 - Elsevier
The reaction mechanisms of direct reductive amination catalyzed by half-sandwich Cp* Ir
complexes and the possible side reactions—transfer hydrogenation of ketones and N …

Осмий-катализируемые восстановительные процессы

КО Бирюков, ОИ Афанасьев, МИ Годовикова… - Успехи химии, 2022 - elibrary.ru
Каталитические восстановительные процессы играют важную роль в органической
химии. К настоящему времени разработано большое число реакций, протекающих при …

The crystal structure of bis(μ2-iodido)-bis(η6-benzene)-bis(iodido)-diosmium(II), C12H12I4Os2

KC Tapala, HS Clayton - Zeitschrift für Kristallographie-New Crystal …, 2022 - degruyter.com
The crystal structure of bis(μ2-iodido)-bis(η6-benzene)-bis(iodido)-diosmium(II), C12H12I4Os2
Skip to content Should you have institutional access? Here's how to get it ... De Gruyter € EUR …