[HTML][HTML] Microbial conversion of syngas to single cell protein: The role of carbon monoxide
Syngas has been widely utilized as substrate in microbial processes to produce various high-
value products. Nevertheless, its applicability for single cell protein (SCP) production by …
value products. Nevertheless, its applicability for single cell protein (SCP) production by …
Syngas Instead of Hydrogen Gas as a Reducing Agent─ A Strategy To Improve the Selectivity and Efficiency of Organometallic Catalysts
E Podyacheva, OI Afanasyev, VS Ostrovskii… - ACS catalysis, 2022 - ACS Publications
Catalytic reduction reactions play a major role in modern chemistry and are often based on
hydrogen gas as a reducing agent. However, the high reactivity of hydrogen is often …
hydrogen gas as a reducing agent. However, the high reactivity of hydrogen is often …
A neutral crystalline imino-substituted silyl radical
FJ Kiefer, A Kostenko, R Holzner, S Inoue - Chemical Communications, 2024 - pubs.rsc.org
The neutral three-coordinated imino (silyl) silyl radical was isolated from the reaction of N-
heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully …
heterocyclic iminosilicon tribromide (ItBuN-SiBr3) with NaSitBu2Me. The radical was fully …
[HTML][HTML] Arene-osmium (II) complexes in homogeneous catalysis
P Crochet, V Cadierno - Inorganics, 2021 - mdpi.com
Although the application of arene-osmium (II) complexes in homogeneous catalysis has
been much less studied than that of their ruthenium analogues, different works have shown …
been much less studied than that of their ruthenium analogues, different works have shown …
Easy Access to Versatile Catalytic Systems for C− H Activation and Reductive Amination Based on Tetrahydrofluorenyl Rhodium (III) Complexes
VB Kharitonov, SA Runikhina… - … A European Journal, 2021 - Wiley Online Library
On the basis of the 1, 2, 3, 4‐tetrahydrofluorenyl ligand, a simple approach was developed
to new effective rhodium catalysts for the construction of C− C and C− N bonds. The halide …
to new effective rhodium catalysts for the construction of C− C and C− N bonds. The halide …
Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power
KO Biriukov, MM Vinogradov, OI Afanasyev… - Catalysis Science & …, 2021 - pubs.rsc.org
Herein, we present the first example of Os-catalyzed efficient reductive amination under
water–gas shift reaction conditions. The developed catalytic systems are formed in situ in …
water–gas shift reaction conditions. The developed catalytic systems are formed in situ in …
Density Functional Theory Study on the Selective Reductive Amination of Aldehydes and Ketones over Their Reductions to Alcohols Using Sodium …
SJ Oliphant, RH Morris - ACS omega, 2022 - ACS Publications
Reductive amination is one of the most important methods to synthesize amines, having a
wide application in the pharmaceutical, fine chemicals, and materials industries. In general …
wide application in the pharmaceutical, fine chemicals, and materials industries. In general …
Theoretical investigation of mechanism and ligand effects on half-sandwich iridium complexes for direct reductive amination
J Wang, C Liu, L Cao, Y Xiong, J Ye, Z Liu, R Cheng - Molecular Catalysis, 2022 - Elsevier
The reaction mechanisms of direct reductive amination catalyzed by half-sandwich Cp* Ir
complexes and the possible side reactions—transfer hydrogenation of ketones and N …
complexes and the possible side reactions—transfer hydrogenation of ketones and N …
Осмий-катализируемые восстановительные процессы
КО Бирюков, ОИ Афанасьев, МИ Годовикова… - Успехи химии, 2022 - elibrary.ru
Каталитические восстановительные процессы играют важную роль в органической
химии. К настоящему времени разработано большое число реакций, протекающих при …
химии. К настоящему времени разработано большое число реакций, протекающих при …
The crystal structure of bis(μ2-iodido)-bis(η6-benzene)-bis(iodido)-diosmium(II), C12H12I4Os2
KC Tapala, HS Clayton - Zeitschrift für Kristallographie-New Crystal …, 2022 - degruyter.com
The crystal structure of bis(μ2-iodido)-bis(η6-benzene)-bis(iodido)-diosmium(II), C12H12I4Os2
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