Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions

K Das, S Waiba, A Jana, B Maji - Chemical Society Reviews, 2022 - pubs.rsc.org
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Multimetallic catalysis based on heterometallic complexes and clusters

P Buchwalter, J Rosé, P Braunstein - Chemical reviews, 2015 - ACS Publications
Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …

[HTML][HTML] A review on commercial-scale high-value products that can be produced alongside cellulosic ethanol

O Rosales-Calderon, V Arantes - Biotechnology for biofuels, 2019 - Springer
The demand for fossil derivate fuels and chemicals has increased, augmenting concerns on
climate change, global economic stability, and sustainability on fossil resources. Therefore …

Transition-metal-catalyzed carbonylation reactions of olefins and alkynes: a personal account

XF Wu, X Fang, L Wu, R Jackstell… - Accounts of Chemical …, 2014 - ACS Publications
Carbon monoxide was discovered and identified in the 18th century. Since the first
applications in industry 80 years ago, academic and industrial laboratories have broadly …

Dehydrogenation and related reactions catalyzed by iridium pincer complexes

J Choi, AHR MacArthur, M Brookhart… - Chemical …, 2011 - ACS Publications
Since the seminal reports by Shaw and co-workers in the mid-1970s, 1-7 the chemistry of
pincer-ligated transition-metal complexes has experienced tremendous development and …

Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis

GE Dobereiner, RH Crabtree - Chemical reviews, 2010 - ACS Publications
The rise of green chemistry has drawn attention to bond construction strategies that promote
atom economy and avoid mutagenic reagents. 1 For example, both goals are achieved by …

Cyclometalation using d-block transition metals: fundamental aspects and recent trends

M Albrecht - Chemical reviews, 2010 - ACS Publications
Cyclometalation refers to the transition metal-mediated activation of a CR bond to form a
metallacycle comprising a new metal-carbon σ bond (Scheme 1). 1, 2 Typically, the reaction …

Dehydrogenative oxidation of alcohols in aqueous media using water-soluble and reusable Cp* Ir catalysts bearing a functional bipyridine ligand

R Kawahara, K Fujita, R Yamaguchi - Journal of the American …, 2012 - ACS Publications
A new catalytic system for the dehydrogenative oxidation of alcohols using a water-soluble
Cp* Ir complex bearing a bipyridine-based functional ligand as catalyst has been …

Cobalt catalysis involving π components in organic synthesis

P Gandeepan, CH Cheng - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Over the last three decades, transition-metal-catalyzed organic transformations
have been shown to be extremely important in organic synthesis. However, most of the …

Water in N-heterocyclic carbene-assisted catalysis

E Levin, E Ivry, CE Diesendruck, NG Lemcoff - Chemical reviews, 2015 - ACS Publications
Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …