Coordinative Chain Transfer and chain shuttling polymerization

R Mundil, C Bravo, N Merle, P Zinck - Chemical Reviews, 2023 - ACS Publications
Coordinative chain transfer polymerization, CCTP, is a degenerative chain transfer
polymerization process that has a wide range of applications. It allows a highly controlled …

From multisite polymerization catalysis to sustainable materials and all-polyolefin composites

M Stürzel, S Mihan, R Mülhaupt - Chemical reviews, 2016 - ACS Publications
Since the pioneering advances of Karl Ziegler and Giulio Natta during the early 1950s, a
continuing series of breakthroughs in research and industrial innovations have greatly …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

iPP/PE Multiblock Copolymers for Plastic Blend Recycling Synthesized by Coordinative Chain Transfer Polymerization

P Wolff, A Dickert, WP Kretschmer, R Kempe - Macromolecules, 2022 - ACS Publications
Recycling of blends of widely used plastics is a key challenge of the envisioned circular
economy, and thus, protocols permitting the efficient synthesis of effective compatibilizers …

Coordinative chain transfer polymerization of 1-decene in the presence of a Ti-based diamine bis (phenolate) catalyst: A sustainable approach to produce low …

A Hanifpour, N Bahri-Laleh… - Green …, 2020 - pubs.rsc.org
A Ti-based diamine bis (phenolate) catalyst,[Ti {2, 2′-(OC6H2-4, 6-tBu2) 2NHMePhMeNH}
Cl2], was synthesized and fully characterized by elemental analysis and NMR spectroscopy …

Highly versatile strategy for the production of telechelic polyolefins

AA Burkey, DM Fischbach, CM Wentz… - ACS Macro …, 2022 - ACS Publications
A general and versatile synthetic strategy for producing practical quantities of a wide range
of phenyl-group-terminated hetero-and homotelechelic semicrystalline polyethenes and …

Coordinative chain transfer copolymerization and terpolymerization of conjugated dienes

S Georges, AO Touré, M Visseaux, P Zinck - Macromolecules, 2014 - ACS Publications
The coordinative chain transfer co-and ter-polymerizations of myrcene, isoprene and styrene
have been achieved using Cp* La (BH4) 2 (THF) 2 (Cp*= pentamethylcyclopentadienyl) …

Stereomodulation of Poly (4‐methyl‐1‐pentene): Adoption of a Neglected and Misunderstood Commercial Polyolefin

CM Wentz, DM Fischbach, LR Sita - Angewandte Chemie, 2022 - Wiley Online Library
A toolbox of living coordination polymerization methods based on CPAM group 4 metal
initiators has been applied for the stereomodulation of poly (4‐methyl‐1‐pentene)(PMP) …

Stereoblock vs Stereoblend: Orchestrating Competing Living Coordination Chain Transfer Polymerizations for the One-Pot Production of New Viscoelastic Grades of …

DM Fischbach, CM Wentz, S Mehdiabadi… - ACS …, 2024 - ACS Publications
By exerting control over two populations of coexisting cyclopentadienyl, amidinate (CPAM)
group 4 metal active species that possess different stereoselectivities for chain growth …

Phenyl-Terminated Polyolefins via Living Coordinative Chain Transfer Polymerization with ZnPh2 as a Chain Transfer Agent

MA Wallace, AA Burkey, LR Sita - ACS Catalysis, 2021 - ACS Publications
Living coordinative chain transfer polymerization (LCCTP) of α-olefins, including propene, 1-
hexene, 1-decene, and 4-methyl-1-pentene, using the Hf pre-initiator 1, the borate co …