Recent progress in hot exciton materials for organic light-emitting diodes

Y Xu, P Xu, D Hu, Y Ma - Chemical Society Reviews, 2021 - pubs.rsc.org
According to Kasha's rule, high-lying excited states usually have little effect on fluorescence.
However, in some molecular systems, the high-lying excited states partly or even mainly …

Delayed fluorescence from inverted singlet and triplet excited states

N Aizawa, YJ Pu, Y Harabuchi, A Nihonyanagi, R Ibuka… - Nature, 2022 - nature.com
Hund's multiplicity rule states that a higher spin state has a lower energy for a given
electronic configuration. Rephrasing this rule for molecular excited states predicts a positive …

Overcoming the limitation of spin statistics in organic light emitting diodes (OLEDs): hot exciton mechanism and its characterization

SW Park, D Kim, YM Rhee - International Journal of Molecular Sciences, 2023 - mdpi.com
Triplet harvesting processes are essential for enhancing efficiencies of fluorescent organic
light-emitting diodes. Besides more conventional thermally activated delayed fluorescence …

Efficient and bright organic radical light‐emitting diodes with low efficiency roll‐off

HH Cho, S Gorgon, HC Hung, JY Huang… - Advanced …, 2023 - Wiley Online Library
Organic radicals have been of interest due to their potential to replace nonradical‐based
organic emitters, especially for deep‐red/near‐infrared (NIR) electroluminescence (EL) …

Deep-blue high-efficiency triplet–triplet annihilation organic light-emitting diodes using hydroxyl-substituted tetraphenylimidazole-functionalized anthracene …

W Li, P Chasing, P Nalaoh… - Journal of Materials …, 2022 - pubs.rsc.org
Herein, two new triplet–triplet annihilation (TTA) molecules, namely HO-PIAC and PIAC, as
deep-blue emitters for high-efficiency TTA-OLEDs were designed and synthesized. HO …

[HTML][HTML] Efficient near-infrared organic light-emitting diodes with emission from spin doublet excitons

HH Cho, S Gorgon, G Londi, S Giannini, C Cho… - Nature …, 2024 - nature.com
The development of luminescent organic radicals has resulted in materials with excellent
optical properties for near-infrared emission. Applications of light generation in this range …

Efficient deep-red Aggregate-Induced emission material and “Hot-exciton” electroluminescence

Y Gao, Y Deng, Y Lv, X Tian, H Liu, ST Zhang… - Chemical Engineering …, 2024 - Elsevier
Organic deep-red fluorescent materials have a wide range of applications in organic light-
emitting diodes (OLEDs), biological imaging, night-vision equipment, and other fields. Here …

Dibenzotropylium-Capped Orthogonal Geometry Enabling Isolation and Examination of a Series of Hydrocarbons with Multiple 14π-Aromatic Units

Y Hayashi, S Suzuki, T Suzuki… - Journal of the American …, 2023 - ACS Publications
A series of six dications composed of pure hydrocarbons with one to six non-substituted 9,
10-anthrylene units end-capped with two dibenzotropyliums were designed and synthesized …

Optoelectronic materials utilizing hot excitons or hot carriers: from mechanism to applications

YT Ding, BY Zhang, CL Sun, Q Wang… - Journal of Materials …, 2023 - pubs.rsc.org
Traditionally, hot excitons or hot carriers generated in semiconductors were considered
unfavourable for many applications, given that they may cause energy loss and device …

Efficient solution-processed OLEDs featuring deep-blue triplet-triplet annihilation emitter based on pyrene derivative

Z Ding, B Ma, Z Zhou, S Zhang, J Pan, W Zhu, Y Liu - Dyes and Pigments, 2023 - Elsevier
Achieving high efficiency deep-blue organic light-emitting diodes (OLEDs) with a CIE y<
0.08 is still terribly urgent yet challenge. Herein, we designed and synthesized a novel blue …