The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …

Alkene-derived radical cations are versatile reactive intermediates and have been widely
applied in the construction of complex functionalized molecules and cyclic systems for …

In recent years, visible light-driven organic photochemical synthesis has attracted wide
research interest from academic and industrial communities due to its features of green and …

Asymmetric hydroalkoxylation of alkenes constitutes a redox-neutral and 100% atom-
economical strategy toward enantioenriched oxygenated building blocks from readily …

Radical cations show a unique reactivity that is fundamentally different from that of
conventional cations and have thus attracted considerable attention as alternative cationic …

With the rapid development of photoredox catalysis, numerous concepts for asymmetric
induction were successfully and broadly adapted from polar two-electron transformations to …

While interest in the synthetic chemistry of radical cations continues to grow, controlling
enantioselectivity in the reactions of these intermediates remains a challenge. Based on …

High acidity and structural confinement are pivotal elements in asymmetric acid catalysis.
The recently introduced imidodiphosphorimidate (IDPi) Brønsted acids have met with …

The activation of olefins for asymmetric chemical synthesis traditionally relies on transition
metal catalysts. In contrast, biological enzymes with Brønsted acidic sites of appropriate …