[HTML][HTML] Penetrant-induced plasticization in microporous polymer membranes

KM Rodriguez, S Lin, AX Wu, KR Storme… - Chemical Society …, 2024 - pubs.rsc.org
Penetrant-induced plasticization has prevented the industrial deployment of many polymers
for membrane-based gas separations. With the advent of microporous polymers, new …

Polymers of intrinsic microporosity and thermally rearranged polymer membranes for highly efficient gas separation

S Bandehali, AE Amooghin, H Sanaeepur… - Separation and …, 2021 - Elsevier
In the last decades, many novel polymeric materials have been considered to prepare highly
energy-efficient gas separation membranes. There is a continuous search to overcome the …

Modeling of gas transport through polymer/MOF interfaces: a microsecond-scale concentration gradient-driven molecular dynamics study

A Ozcan, R Semino, G Maurin… - Chemistry of …, 2020 - ACS Publications
Membrane-based separation technologies offer a cost-effective alternative to many energy-
intensive gas separation processes, such as distillation. Mixed matrix membranes (MMMs) …

[HTML][HTML] Molecular modeling investigations of sorption and diffusion of small molecules in Glassy polymers

N Vergadou, DN Theodorou - Membranes, 2019 - mdpi.com
With a wide range of applications, from energy and environmental engineering, such as in
gas separations and water purification, to biomedical engineering and packaging, glassy …

[HTML][HTML] Sorption-enhanced mixed-gas transport in amine functionalized polymers of intrinsic microporosity (PIMs)

KM Rodriguez, FM Benedetti, N Roy, AX Wu… - Journal of Materials …, 2021 - pubs.rsc.org
Pure-gas transport performance rarely matches mixed-gas performance for industrially
relevant membrane applications. While significant effort has focused on studying the …

[HTML][HTML] Modelling sorption and transport of gases in polymeric membranes across different scales: a review

E Ricci, M Minelli, MG De Angelis - Membranes, 2022 - mdpi.com
Professor Giulio C. Sarti has provided outstanding contributions to the modelling of fluid
sorption and transport in polymeric materials, with a special eye on industrial applications …

Carbon molecular sieve gas separation materials and membranes: A comprehensive review

G Genduso, W Ogieglo, Y Wang, I Pinnau - Journal of Membrane Science, 2024 - Elsevier
Carbon molecular sieve (CMS) membranes offer some of the best combinations of high
selectivity and permeability for molecular separations of permanent and condensable gases …

Competitive sorption in CO2/CH4 separations: The case of HAB-6FDA polyimide and its TR derivative and a general analysis of its impact on the selectivity of glassy …

E Ricci, FM Benedetti, ME Dose, MG De Angelis… - Journal of Membrane …, 2020 - Elsevier
CO 2 and CH 4 mixed-gas solubility was measured in 3, 3′-dihydroxy-4, 4′-diamino-
biphenyl (HAB) 2, 2′-bis-(3, 4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) …

Permeation, sorption, and diffusion of CO2-CH4 mixtures in polymers of intrinsic microporosity: The effect of intrachain rigidity on plasticization resistance

G Genduso, Y Wang, BS Ghanem, I Pinnau - Journal of Membrane Science, 2019 - Elsevier
Abstract CO 2-CH 4 mixed-gas sorption and permeation properties of a ladder polymer (PIM-
Trip-TB) were measured experimentally at 35° C to interpret nonideal transport behavior of …

[HTML][HTML] Experimental Mixed-Gas Permeability, Sorption and Diffusion of CO2-CH4 Mixtures in 6FDA-mPDA Polyimide Membrane: Unveiling the Effect of …

G Genduso, BS Ghanem, I Pinnau - Membranes, 2019 - mdpi.com
The nonideal behavior of polymeric membranes during separation of gas mixtures can be
quantified via the solution-diffusion theory from experimental mixed-gas solubility and …