Critical review on the degradation mechanisms and recent progress of Ni-rich layered oxide cathodes for lithium-ion batteries

Q Gan, N Qin, H Yuan, L Lu, Z Xu, Z Lu - EnergyChem, 2023 - Elsevier
Ni-rich layered transition metal oxides possess remarkably high capacity and thus are very
competitive cathode materials in high-energy lithium-ion batteries (LIBs) for electric vehicles …

High nickel and no cobalt─ the pursuit of next-generation layered oxide cathodes

L Yu, T Liu, R Amine, J Wen, J Lu… - ACS Applied Materials & …, 2022 - ACS Publications
The prosperity of the electric vehicle industry is driving the research and development of
lithium-ion batteries. As one of the core components in the entire battery system, cathode …

Gradient boracic polyanion doping-derived surface lattice modulation of high-voltage Ni-rich layered cathodes for high-energy-density Li-ion batteries

F Li, Z Liu, C Liao, X Xu, M Zhu, J Liu - ACS Energy Letters, 2023 - ACS Publications
The utilization of high-voltage Ni-rich cathodes can cost-effectively push lithium-ion batteries
toward higher energy density but suffers from major challenges with severe structural and …

Long‐Range Cationic Disordering Induces two Distinct Degradation Pathways in Co‐Free Ni‐Rich Layered Cathodes

W Hua, J Zhang, S Wang, Y Cheng, H Li… - Angewandte …, 2023 - Wiley Online Library
Ni‐rich layered oxides are one of the most attractive cathode materials in high‐energy‐
density lithium‐ion batteries, their degradation mechanisms are still not completely …

Regulating surface oxygen activity by perovskite‐coating‐stabilized ultrahigh‐nickel layered oxide cathodes

L Wang, G Liu, R Wang, X Wang, L Wang… - Advanced …, 2023 - Wiley Online Library
Ultrahigh‐Ni layered oxides are proposed as promising cathodes to fulfill the range demand
of electric vehicles; yet, they are still haunted by compromised cyclability and thermal …

Twin Boundaries Contribute to The First Cycle Irreversibility of LiNiO2

H Nguyen, R Silverstein, A Zaveri, W Cui… - Advanced Functional …, 2023 - Wiley Online Library
LiNiO2 remains a target for layered oxide Li‐ion cathode development as it can theoretically
deliver the highest energy density of this materials class. In practice, LiNiO2 suffers from …

Cobalt-free composite-structured cathodes with lithium-stoichiometry control for sustainable lithium-ion batteries

K Chen, P Barai, O Kahvecioglu, L Wu… - Nature …, 2024 - nature.com
Lithium-ion batteries play a crucial role in decarbonizing transportation and power grids, but
their reliance on high-cost, earth-scarce cobalt in the commonly employed high-energy …

Oxygen-Redox Activity in Non-Lithium-Excess Tungsten-Doped Cathode

AS Menon, BJ Johnston, SG Booth, L Zhang, K Kress… - PRX Energy, 2023 - APS
The desire to increase the energy density of stoichiometric layered Li TM O 2 (TM= 3 d
transition metal) cathode materials has promoted investigation into their properties at high …

A Practical and Sustainable Ni/Co-Free High-Energy Electrode Material: Nanostructured LiMnO2

Y Miyaoka, T Sato, Y Oguro, S Kondo… - ACS Central …, 2024 - ACS Publications
Ni/Co-free high-energy positive electrode materials are of great importance to ensure the
sustainability of Li-ion battery production and its supply chain in addition to minimizing …

Understanding the High Voltage Behavior of LiNiO2 Through the Electrochemical Properties of the Surface Layer

E Bautista Quisbert, F Fauth, AM Abakumov… - Small, 2023 - Wiley Online Library
Nickel‐rich layered oxides are adopted as electrode materials for EV's. They suffer from a
capacity loss when the cells are charged above 4.15 V versus Li/Li+. Doping and coating …