Perfluoroalkyl groups containing bicyclo [1.1. 1] pentanes (BCPs) are gaining increasing
interest in the pharmaceutical industry and materials science; however, the development of …

Strategies commonly used for the synthesis of functionalised bicyclo [1.1. 1] pentanes (BCP)
rely on the reaction of [1.1. 1] propellane with anionic or radical intermediates. In contrast …

We report a range of highly regioselective openings of [1.1. 1] propellane with various allylic
zinc halides, as well as zinc enolates of ketones, esters and nitriles. The resulting zincated …

Herein, we report the metal-free synthesis of imidized methylene cyclobutane derivatives via
a strain-release driven addition reaction of [1.1. 1] propellane. Using this strategy, the …

[1.1. 1] Propellane is the ubiquitous precursor to bicyclo [1.1. 1] pentanes (BCPs), motifs of
high value in pharmaceutical and materials research. The classical Lewis representation of …

During the Search for a relationship between boranes and allotropes of elemental boron,
several chemical problems came up: mechanism of 1, 2‐shift in vinyl cations, relative …

Herein, we report the metal-free synthesis of methylenecyclobutane containing
tetrasubstituted alkenyl nitriles via a strain-release driven addition reaction of [1.1. 1] …

The ability of organic and inorganic compounds bearing both iodine and astatine atoms to
form halogen-bond interactions is theoretically investigated. Upon inclusion of the relativistic …

A coinage-metal bond has been predicted and characterized in the complexes of [1.1. 1]
propellane (P) and M2/MCl/MCH3 (M= Cu, Ag, and Au). The interaction energy varies …

Chemical bond territory is rich with covalently bonded molecules wherein a strong bond is
formed by equal or unequal sharing of a quantum of electrons. The noncovalent version of …