Understanding glass through differential scanning calorimetry

Q Zheng, Y Zhang, M Montazerian, O Gulbiten… - Chemical …, 2019 - ACS Publications
Differential scanning calorimetry (DSC) is a powerful tool to address some of the most
challenging issues in glass science and technology, such as the nonequilibrium nature of …

Theory of structural glasses and supercooled liquids

V Lubchenko, PG Wolynes - Annu. Rev. Phys. Chem., 2007 - annualreviews.org
We review the random first-order transition theory of the glass transition, emphasizing the
experimental tests of the theory. Many distinct phenomena are quantitatively predicted or …

A metal-organic framework with ultrahigh glass-forming ability

A Qiao, TD Bennett, H Tao, A Krajnc, G Mali… - Science …, 2018 - science.org
Glass-forming ability (GFA) is the ability of a liquid to avoid crystallization during cooling.
Metal-organic frameworks (MOFs) are a new class of glass formers (1–3), with hitherto …

Hybrid glasses from strong and fragile metal-organic framework liquids

TD Bennett, JC Tan, Y Yue, E Baxter, C Ducati… - Nature …, 2015 - nature.com
Hybrid glasses connect the emerging field of metal-organic frameworks (MOFs) with the
glass formation, amorphization and melting processes of these chemically versatile systems …

Direct experimental evidence of a growing length scale accompanying the glass transition

L Berthier, G Biroli, JP Bouchaud, L Cipelletti, DE Masri… - Science, 2005 - science.org
Understanding glass formation is a challenge, because the existence of a true glass state,
distinct from liquid and solid, remains elusive: Glasses are liquids that have become too …

Glass transition thermodynamics and kinetics

FH Stillinger, PG Debenedetti - Annu. Rev. Condens. Matter …, 2013 - annualreviews.org
The remarkable kinetic slowdown experienced by liquids as they are cooled toward their
glass transition is not accompanied by any obvious structural change. Understanding the …

Measurement of growing dynamical length scales and prediction of the jamming transition in a granular material

AS Keys, AR Abate, SC Glotzer, DJ Durian - Nature physics, 2007 - nature.com
Supercooled liquids and dense colloidal suspensions exhibit anomalous behaviour known
as 'spatially heterogeneous dynamics'(SHD), which becomes increasingly pronounced as …

Fragility and thermodynamics in nonpolymeric glass-forming liquids

LM Wang, CA Angell, R Richert - The Journal of chemical physics, 2006 - pubs.aip.org
For nonpolymeric supercooled liquids, the empirical correlation m= 56 T g Δ C p (T g)∕ Δ H
m provides a reliable means of correlating dynamic and thermodynamic variables. The …

Oxygen molecule dissociation on carbon nanostructures with different types of nitrogen doping

S Ni, Z Li, J Yang - Nanoscale, 2012 - pubs.rsc.org
The energy barrier of oxygen molecule dissociation on carbon nanotubes or graphene with
different types of nitrogen doping is investigated using density functional theory. The results …

The shapes of cooperatively rearranging regions in glass-forming liquids

JD Stevenson, J Schmalian, PG Wolynes - Nature Physics, 2006 - nature.com
The cooperative rearrangement of groups of many molecules has long been thought to
underlie the dramatic slowing of liquid dynamics on cooling towards the glassy state. For …