Selective C–C and C–O bond cleavage strategies for the thermochemical upgrading of (hemi) cellulosic biomass
Utilizing lignocellulose as an alternative green carbon resource is recognized as a vital
approach to drive the ongoing transition towards a sustainable manufacture of chemicals …
approach to drive the ongoing transition towards a sustainable manufacture of chemicals …
The deoxydehydration (DODH) reaction: a versatile technology for accessing olefins from bio-based polyols
NN Tshibalonza, JCM Monbaliu - Green Chemistry, 2020 - pubs.rsc.org
This review provides a complete overview of the deoxydehydration (DODH) reaction
including metal-free and transition metal-based DODH processes for the upgrading of bio …
including metal-free and transition metal-based DODH processes for the upgrading of bio …
Transition metal-catalyzed deoxydehydration: missing pieces of the puzzle
FC Jentoft - Catalysis Science & Technology, 2022 - pubs.rsc.org
Deoxydehydration (DODH) is a transformation that converts a vicinal diol into an olefin with
the help of a sacrificial reductant. The reaction has drawn interest in the past 25 years for its …
the help of a sacrificial reductant. The reaction has drawn interest in the past 25 years for its …
Deoxydehydration of Biomass‐Derived Polyols Over Silver‐Modified Ceria‐Supported Rhenium Catalyst with Molecular Hydrogen
K Yamaguchi, J Cao, M Betchaku, Y Nakagawa… - …, 2022 - Wiley Online Library
Olefin production from polyols via deoxydehydration (DODH) was carried out over Ag‐
modified CeO2‐supported heterogeneous Re catalysts with H2 as a reducing agent. Both …
modified CeO2‐supported heterogeneous Re catalysts with H2 as a reducing agent. Both …
Kinetic Modeling of Erythritol Deoxydehydration and Consecutive Hydrogenation over the ReOx-Pd/CeO2 Catalyst
The reaction kinetics of deoxydehydration+ hydrogenation (DODH+ HG; didehydroxylation)
of erythritol to butanediols and n-butane over the ReO x-Pd/CeO2 catalyst was investigated …
of erythritol to butanediols and n-butane over the ReO x-Pd/CeO2 catalyst was investigated …
Titania-supported molybdenum oxide combined with Au nanoparticles as a hydrogen-driven deoxydehydration catalyst of diol compounds
A heterogenous catalyst for the deoxydehydration (DODH) reaction was developed using
less expensive Mo than Re as the active center. The combination of Mo with anatase-rich …
less expensive Mo than Re as the active center. The combination of Mo with anatase-rich …
One-step production of renewable adipic acid esters from mucic acid over an Ir–ReO x/C catalyst with low Ir loading
The production of adipic acid, a large-volume platform chemical, from biomass represents a
petroleum-free route to manufacturing nylon and other polymers more sustainably. In this …
petroleum-free route to manufacturing nylon and other polymers more sustainably. In this …
A Heterogeneous Pt-ReOx/C Catalyst for Making Renewable Adipates in One Step from Sugar Acids
Renewable adipic acid is a value-added chemical for the production of bioderived nylon.
Here, the one-step conversion of mucic acid to adipates was achieved in high yield through …
Here, the one-step conversion of mucic acid to adipates was achieved in high yield through …
Mechanistic Study on Deoxydehydration and Hydrogenation of Methyl Glycosides to Dideoxy Sugars over a ReOx–Pd/CeO2 Catalyst
J Cao, M Tamura, R Hosaka, A Nakayama… - ACS …, 2020 - ACS Publications
We found that nonprotected methyl glycosides with cis-vicinal OH groups could be
converted to the corresponding methyl dideoxy glycosides by deoxydehydration and …
converted to the corresponding methyl dideoxy glycosides by deoxydehydration and …
Recent advances in the deoxydehydration of vicinal diols and polyols
LJ Donnelly, SP Thomas… - Chemistry–An Asian …, 2019 - Wiley Online Library
Deoxydehydration (DODH) is one of the most promising tools to reduce the oxygen content
of biomass (sugars and polyols) and provide analogues of platform chemicals that are …
of biomass (sugars and polyols) and provide analogues of platform chemicals that are …