Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

Pd-catalyzed cross-coupling reactions have become essential tools for the construction of
carbon–carbon and carbon–heteroatom bonds. Over the last three decades, great efforts …

We review here new developments in decreasing the catalyst loadings in palladium‐
catalyzed C–C bond‐formation reactions to mol ppm or mol ppb levels. This decreases the …

The Sonogashira reaction is a cross-coupling reaction of a vinyl or aryl halide with a terminal
alkyne to form a C–C bond. In its original form, the Sonogashira reaction is performed with a …

This review article will consider the preparation and application of ynones in synthetic
organic chemistry. Concerning the preparation of these bifunctional compounds, several …

A comprehensive and up-to-date overview of alkyne chemistry, taking into account the
progress made over the last two decades. The experienced editors are renowned world …

Despite the success of Sonogashira coupling for the synthesis of arylalkynes and
conjugated enynes, the engagement of unactivated alkyl halides in such reactions remains …

Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …

Highly dispersed Pd (0) nanoparticles were successfully immobilized into a stable,
crystalline and porous covalent organic framework (COF), TpPa-1, by a solution infiltration …

Comprehensive Summary Sonogashira cross‐coupling protocol, typically showing the
reaction between aryl/vinyl halide and terminal alkyne, has been a widely used protocol for …