Fundamental research on germanium as the central element in compounds for bond
activation chemistry and catalysis has achieved significant feats over the last two decades …

Recent years have witnessed remarkable advances in radical reactions involving main‐
group metal complexes. This includes the isolation and detailed characterization of main …

Tetryliumylidene ions ([R–E:]+), recognised for their intriguing electronic properties, have
attracted considerable interest. These positively charged species, with two vacant p-orbitals …

By use of the ethylene-bridged bidentate bis-NHI (NHI= N-heterocyclic imine) ligand 1
toward the complexation of ECl2·(dioxane)(E= Ge, Sn) the synthesis of the first bis-NHI …

Ge( ii ) cation catalyzed hydroboration of aldehydes and ketones - Dalton Transactions (RSC
Publishing) DOI:10.1039/C8DT05121F Royal Society of Chemistry View PDF VersionPrevious …

The N-heterocyclic germylenes and stannylenes LSi (NAr) 2EX (L= PhC (N t Bu) 2, Ar= 2, 6-i
Pr2C6H3; E= Ge, Sn; X= Cl, CF3SO3, BPh4) supported by the bulky silaamidinate ligand …

Bis (chlorotetrylene) s of Si, Ge, and Sn have been synthetically realized starting from the
backbone‐bridged bis (amidine) 1. Double deprotonation of 1 and subsequent reaction with …

The ambiphilic Ge (II) and Sn (II) cationic species have been reported to be isolated through
kinetic or thermodynamic stabilizations. Nonetheless, steric congestion or excessive …

A naphthyridine diimine (NDI) supported bis (germylene) NDI-Ge2 containing two
dicoordinate, coplanar Ge (II) atoms has been synthesised. Computational investigations on …

The adaptability of three acyclic tetradentate ligands with the–CHR–CHR–(R= H or alkyl
substituent) linker in the backbone: bis (α-iminopyridine) L1 and the reduced form L2 and …