[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR
ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …
diversification since its inception more than 6 decades ago. In this review we provide an in …
Recent developments in MAS DNP-NMR of materials
AGM Rankin, J Trébosc, F Pourpoint… - Solid State Nuclear …, 2019 - Elsevier
Solid-state NMR spectroscopy is a powerful technique for the characterization of the atomic-
level structure and dynamics of materials. Nevertheless, the use of this technique is often …
level structure and dynamics of materials. Nevertheless, the use of this technique is often …
Efficient dynamic nuclear polarization at 800 MHz/527 GHz with trityl‐nitroxide biradicals
Cross‐effect (CE) dynamic nuclear polarization (DNP) is a rapidly developing technique that
enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE …
enhances the signal intensities in magic‐angle spinning (MAS) NMR spectra. We report CE …
Towards efficient and stable donor‐acceptor luminescent radicals
C Lu, E Cho, Z Cui, Y Gao, W Cao… - Advanced …, 2023 - Wiley Online Library
In contrast to closed‐shell luminescent molecules, the electronic ground state and lowest
excited state in organic luminescent radicals are both spin doublet, which results in spin …
excited state in organic luminescent radicals are both spin doublet, which results in spin …
Tailoring of Polarizing Agents in the bTurea Series for Cross‐Effect Dynamic Nuclear Polarization in Aqueous Media
C Sauvée, G Casano, S Abel… - … A European Journal, 2016 - Wiley Online Library
A series of 18 nitroxide biradicals derived from bTurea has been prepared, and their
enhancement factors ɛ (1H) in cross‐effect dynamic nuclear polarization (CE DNP) NMR …
enhancement factors ɛ (1H) in cross‐effect dynamic nuclear polarization (CE DNP) NMR …
[HTML][HTML] Cellular solid-state NMR investigation of a membrane protein using dynamic nuclear polarization
K Yamamoto, MA Caporini, SC Im, L Waskell… - … et Biophysica Acta (BBA …, 2015 - Elsevier
While an increasing number of structural biology studies successfully demonstrate the
power of high-resolution structures and dynamics of membrane proteins in fully …
power of high-resolution structures and dynamics of membrane proteins in fully …
Biomolecular DNP‐Supported NMR Spectroscopy using Site‐Directed Spin Labeling
EAW van Der Cruijsen, EJ Koers… - … A European Journal, 2015 - Wiley Online Library
Dynamic nuclear polarization (DNP) has been shown to greatly enhance spectroscopic
sensitivity, creating novel opportunities for NMR studies on complex and large molecular …
sensitivity, creating novel opportunities for NMR studies on complex and large molecular …
Optimizing nitroxide biradicals for cross-effect MAS-DNP: the role of g-tensors' distance
F Mentink-Vigier - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
Nitroxide biradicals are common polarizing agents used to enhance the sensitivity of solid-
state NMR experiments via Magic Angle Spinning Dynamic Nuclear Polarization (MAS …
state NMR experiments via Magic Angle Spinning Dynamic Nuclear Polarization (MAS …
bcTol: a highly water-soluble biradical for efficient dynamic nuclear polarization of biomolecules
AP Jagtap, MA Geiger, D Stöppler… - Chemical …, 2016 - pubs.rsc.org
Dynamic nuclear polarization (DNP) is an efficient method to overcome the inherent low
sensitivity of magic-angle spinning (MAS) solid-state NMR. We report a new polarizing agent …
sensitivity of magic-angle spinning (MAS) solid-state NMR. We report a new polarizing agent …
De novo prediction of cross-effect efficiency for magic angle spinning dynamic nuclear polarization
F Mentink-Vigier, AL Barra, J Van Tol… - Physical Chemistry …, 2019 - pubs.rsc.org
Magic angle spinning dynamic nuclear polarization (MAS-DNP) has become a key
approach to boost the intrinsic low sensitivity of NMR in solids. This method relies on the use …
approach to boost the intrinsic low sensitivity of NMR in solids. This method relies on the use …