Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres
Bicycloalkanes, cubanes and their structural analogues have emerged as bioisosteres of
(hetero) arenes. To meet increasing demand, the chemical community has developed a …
(hetero) arenes. To meet increasing demand, the chemical community has developed a …
The rational design of reducing organophotoredox catalysts unlocks proton-coupled electron-transfer and atom transfer radical polymerization mechanisms
T Bortolato, G Simionato, M Vayer… - Journal of the …, 2023 - ACS Publications
Photocatalysis has become a prominent tool in the arsenal of organic chemists to develop
and (re) imagine transformations. However, only a handful of versatile organic …
and (re) imagine transformations. However, only a handful of versatile organic …
Π–Π Stacking complex induces three‐component coupling reactions to synthesize functionalized amines
Abstract π‐π stacking and ion‐pairing interactions induced the generation of α‐amino
radicals under the irradiation of visible light without the requirement of an expensive …
radicals under the irradiation of visible light without the requirement of an expensive …
o-Phosphinodiarylamides as Reductive Photocatalysts for Dehalogenative and Deaminative Cross-Couplings
The strong electron-donating ability in the photoactivated state and the structural flexibility of
organic anions have led to a growing interest in utilizing photoexcited organic anions as …
organic anions have led to a growing interest in utilizing photoexcited organic anions as …
A general organophotoredox strategy to difluoroalkyl bicycloalkane (CF2‐BCA) Hybrid Bioisosteres
Here, we report a general approach to the synthesis of the difluoroalkyl bicycloalkanes (CF2‐
BCAs), as structural surrogates of aryl ketones and ethers. The chemistry is driven by a …
BCAs), as structural surrogates of aryl ketones and ethers. The chemistry is driven by a …
Strategies for transferring photobiocatalysis to continuous flow exemplified by photodecarboxylation of fatty acids
S Simic, M Jakstaite, WTS Huck, CK Winkler… - ACS catalysis, 2022 - ACS Publications
The challenges of light-dependent biocatalytic transformations of lipophilic substrates in
aqueous media are manifold. For instance, photolability of the catalyst as well as insufficient …
aqueous media are manifold. For instance, photolability of the catalyst as well as insufficient …
Phenols as Novel Photocatalytic Platforms for Organic Synthesis
In recent years, organic chemists have devoted a great deal of effort towards the
implementation of novel green photocatalytic synthetic protocols. To this end, the …
implementation of novel green photocatalytic synthetic protocols. To this end, the …
A visible-light-promoted metal-free approach for N–H insertions by using donor/donor diazo precursors
The metal-catalyzed carbenoid-based N–H insertions of α-stabilized diazo compounds and
relative precursors serve as robust strategies for the formation of C–N bonds. However …
relative precursors serve as robust strategies for the formation of C–N bonds. However …
Catalytic Photoredox Carbobromination of Unactivated Alkenes with α-Bromocarbonyls via the Mechanistically Distinct Radical-Addition Radical-Pairing Pathway
We disclose a catalytic photoredox carbobromination of unactivated alkenes with α-
bromocarbonyl compounds under blue-light-emitting diode (LED) light. The reaction …
bromocarbonyl compounds under blue-light-emitting diode (LED) light. The reaction …
An Organocatalytic System for Z-Alkene Synthesis via a Hydrogen-Bonding-Assisted Photoinduced Electron Donor–Acceptor Complex
H Zhao, Y Zong, Y Sun, G An, J Wang - Organic Letters, 2024 - ACS Publications
A general catalytic donor for the combination of a photoinduced electron donor–acceptor
(EDA) complex and energy transfer was developed. This mild and metal-free protocol allows …
(EDA) complex and energy transfer was developed. This mild and metal-free protocol allows …