Electrides are materials in which electrons serve as anions. Here, the concept of inorganic
electrides is extended in several respects: from ionic crystals to intermetallic compounds in …

Fluorine has emerged as a “magic element” in medicinal chemistry, crop, and materials
science. 1 Although fluorine is the most abundant halogen in the earth's crust, it is contained …

Incorporation of fluoroalkyl motifs in pharmaceuticals can enhance the therapeutic profiles of
the parent molecules. The hydrofluoroalkylation of alkenes has emerged as a promising …

Conspectus Owing to their unique biological, physical, and chemical properties,
fluoroalkylated organic substances have attracted significant attention from researchers in a …

A selection of perfluoroalkylation reactions of aliphatic substrates that display
methodological and synthetic amplitude will be studied, giving examples of their …

The difunctionalizative trifluoromethylation of unsaturated C− C bonds is a highly useful and
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …

The selective hydrofluorocarbofunctionalization of alkenes is an important synthetic strategy
for efficiently constructing fluorine-containing compounds. However, existing methods often …

Because of their loosely bound electrons, electrides offer physical properties useful in
chemical synthesis and electronics. For these applications and others, nanosized electrides …

A Pd-catalyzed three component reaction involving terminal alkynes, boronic acids, and
perfluoroalkyl iodides is presented here. Trisubstituted perfluoroalkenes can be obtained in …

The development of catalyst-controlled stereoselective olefin metathesis processes has
been a pivotal recent advance in chemistry. The incorporation of appropriate ligands within …