Catalytic strategies and mechanism analysis orbiting the center of critical intermediates in lignin depolymerization

C Zhang, X Shen, Y Jin, J Cheng, C Cai… - Chemical …, 2023 - ACS Publications
Lignin, as a precious resource given to mankind by nature with abundant functional aromatic
structures, has drawn much attention in the recent decade from academia to industry …

A bifunctional brønsted acidic deep eutectic solvent to dissolve and catalyze the depolymerization of alkali lignin

L Li, Z Wu, X Xi, B Liu, Y Cao, H Xu… - Journal of Renewable …, 2021 - ingentaconnect.com
Lignin is an abundant renewable macromolecular material in nature, and degradation of
lignin to improve its hydroxyl content is the key to its efficient use. Alkali lignin (AL) was …

Bond cleavage of lignin model compounds into aromatic monomers using supported metal catalysts in supercritical water

A Yamaguchi, N Mimura, M Shirai, O Sato - Scientific reports, 2017 - nature.com
More efficient use of lignin carbon is necessary for carbon-efficient utilization of
lignocellulosic biomass. Conversion of lignin into valuable aromatic compounds requires the …

Visible-light-driven efficient cleavage of β-O-4 linkage in a lignin model compound: Phenethyl phenyl ether photocatalyzed by titanium nitride nanoparticles

Z Liu, Y Huang, G Xiao, P Li, H Su, S Sarina… - Energy & Fuels, 2021 - ACS Publications
Producing valuable aromatics from lignin through controlled depolymerization has attracted
much attention recently, especially with β-O-4 linkage as the key target, which accounts for …

Roles of Na2CO3 in lignite hydroliquefaction with Fe-based catalyst

L Li, S Huang, SY Wu, YQ Wu, JS Gao - Fuel Processing Technology, 2015 - Elsevier
In this paper, the roles of Na 2 CO 3 were investigated mainly for the lignite
hydroliquefaction process with Fe-based catalyst. As a whole, Na 2 CO 3 could play a …

Zirconia catalysts (ZrO2 and Na-ZrO2) for the conversion of phenethyl phenyl ether (PPE) in supercritical water

HJ Eom, MS Kim, DW Lee, YK Hong, G Jeong… - Applied Catalysis A …, 2015 - Elsevier
In this study, the mesoporous ZrO 2 and Na-ZrO 2 were examined as heterogeneous solid
catalysts under supercritical water for the β-ether bond scission of phenethyl phenyl ether …

Effect of catalyst and atmosphere on liquefaction performance of the lignite in optimized two-stage liquefaction process

J Qian, Y Wu, S Huang, S Wu, R Zhao, J Gao - Fuel, 2022 - Elsevier
Since most oxygen containing structures in lignite will break at relatively low temperature
and macromolecular structure will pyrolyze at higher temperatures, two-stage liquefaction …

Investigation of hydrothermal depolymerization of lignite under different conditions by 13C-NMR spectroscopy

P Zhu, Z Wang, C Pan, ZK Li, W Zhang, J Yan… - Journal of Analytical and …, 2024 - Elsevier
Efficient depolymerization of lignite under mild conditions is the key to realizing its low
carbon conversion and high value utilization. This study focuses on three Chinese lignites …

Reaction analysis of diaryl ether decomposition under hydrothermal conditions

D Alam, MY Lui, A Yuen, T Maschmeyer… - Industrial & …, 2018 - ACS Publications
The reactivity and decomposition pathway of models for α-O-4 and β-O-4 linkages, found
within lignin, have been examined using methoxy-substituted (− OCH3) and-unsubstituted …

Comparative Study of the Catalytic Performances of Na2CO3 and γ-FeOOH in Hydroliquefaction To Propose a Two-Stage Lignite Catalytic Liquefaction Process

R Zhao, S Huang, Y Wu, S Wu, J Gao - Energy & fuels, 2019 - ACS Publications
High oxygen content in lignite increases hydrogen consumption during hydroliquefaction,
and simultaneously the produced water decreases hydrogen partial pressure, which …