Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry

L Buglioni, F Raymenants, A Slattery… - Chemical …, 2021 - ACS Publications
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …

Ligand‐to‐metal charge transfer (LMCT) photochemistry at 3d‐metal complexes: an emerging tool for sustainable organic synthesis

F Juliá - ChemCatChem, 2022 - Wiley Online Library
Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

[HTML][HTML] Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2

L Song, W Wang, JP Yue, YX Jiang, MK Wei… - Nature Catalysis, 2022 - nature.com
High value utilization of carbon dioxide (CO2) has attracted worldwide attention for decades.
Catalytic carboxylation of alkenes with CO2 to synthesize valuable carboxylic acids and …

Strategic use of visible-light photoredox catalysis in natural product synthesis

SP Pitre, LE Overman - Chemical Reviews, 2021 - ACS Publications
Recent progress in the development of photocatalytic reactions promoted by visible light is
leading to a renaissance in the use of photochemistry in the construction of structurally …

Semi-heterogeneous gC 3 N 4/NaI dual catalytic C–C bond formation under visible light

HY Song, J Jiang, C Wu, JC Hou, YH Lu, KL Wang… - Green …, 2023 - pubs.rsc.org
The semi-heterogeneous g-C3N4/NaI dual catalytic system-driven C–C bond formation
between quinoxalin-2 (1H)-ones and arylhydrazines under blue light irradiation has been …

Current technologies for plastic waste treatment: A review

F Zhang, Y Zhao, D Wang, M Yan, J Zhang… - Journal of Cleaner …, 2021 - Elsevier
Conventional nonbiodegradable plastic waste (NPW) treatment technologies include landfill
and incineration, which face bottlenecks and cannot solve NPW problems effectively …

Natural sunlight photocatalytic synthesis of benzoxazole-bridged covalent organic framework for photocatalysis

CJ Wu, XY Li, TR Li, MZ Shao, LJ Niu… - Journal of the …, 2022 - ACS Publications
Although natural sunlight-mediated photocatalysis is a clean, efficient, and green approach
to access organic products, its application in the synthesis of covalent organic frameworks …

Visible‐light‐induced homolysis of earth‐abundant metal‐substrate complexes: A complementary activation strategy in photoredox catalysis

Y Abderrazak, A Bhattacharyya… - Angewandte Chemie …, 2021 - Wiley Online Library
The mainstream applications of visible‐light photoredox catalysis predominately involve
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …

Generation of alkyl radicals: from the tyranny of tin to the photon democracy

S Crespi, M Fagnoni - Chemical reviews, 2020 - ACS Publications
Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …

[HTML][HTML] Copper-photocatalyzed ATRA reactions: concepts, applications, and opportunities

S Engl, O Reiser - Chemical Society Reviews, 2022 - pubs.rsc.org
Atom transfer radical addition (ATRA) reactions are linchpin transformations in synthetic
chemistry enabling the atom-economic difunctionalization of alkenes. Thereby a rich …