Functional supramolecular systems: Design and applications

IS Antipin, MV Alfimov, VV Arslanov… - Russian Chemical …, 2021 - iopscience.iop.org
The interest in functional supramolecular systems for the design of innovative materials and
technologies, able to fundamentally change the world, is growing at a high pace. The huge …

Supramolecular catalysis. Part 2: artificial enzyme mimics

M Raynal, P Ballester, A Vidal-Ferran… - Chemical Society …, 2014 - pubs.rsc.org
The design of artificial catalysts able to compete with the catalytic proficiency of enzymes is
an intense subject of research. Non-covalent interactions are thought to be involved in …

Confining phosphanes derived from cyclodextrins for efficient regio‐and enantioselective hydroformylation

M Jouffroy, R Gramage‐Doria, D Armspach… - Angewandte …, 2014 - Wiley Online Library
Two confining phosphane ligands derived from either α‐or β‐cyclodextrin produce singly PIII‐
ligated metal complexes with unusual coordination spheres. High‐pressure NMR studies …

Aqueous biphasic hydroformylation and hydroaminomethylation assisted by cyclodextrins: From benchtop to industrial perspective

M Ferreira, H Bricout, TFH Roth, T Seidensticker… - Catalysis Today, 2024 - Elsevier
Hydroformylation is an important industrial process that produces aldehydes from alkenes
and syngas in accordance with the atom economy principle. Hydroaminomethylation, on the …

Programmed Synthesis of Hepta‐Differentiated β‐Cyclodextrin: 1 out of 117655 Arrangements

J Liu, B Wang, C Przybylski… - Angewandte Chemie …, 2021 - Wiley Online Library
Cyclodextrin poly‐functionalization has fueled progress in their use in multiple applications
such as enzyme mimicry, but also in the polymer sciences, luminescence, as sensors or for …

Synthesis of Hydrophilic Phosphorus Ligands and Their Application in Aqueous‐Phase Metal‐Catalyzed Reactions

T Schlatzer, R Breinbauer - Advanced Synthesis & Catalysis, 2021 - Wiley Online Library
Transition metal‐catalyzed reactions in aqueous media are experiencing a constant
increase in interest. In homogenous catalysis the use of water as a solvent offers …

Low melting mixtures based on β-cyclodextrin derivatives and N, N′-dimethylurea as solvents for sustainable catalytic processes

F Jérôme, M Ferreira, H Bricout, S Menuel… - Green …, 2014 - pubs.rsc.org
β-Cyclodextrin series and N, N′-dimethylurea formed low melting mixtures able to
immobilize organometallic species based on sulfonated phosphanes. Hydroformylation and …

Phosphines and other P (III)‐derivatives with cavity‐shaped subunits: valuable ligands for supramolecular metal catalysis, metal confinement and subtle steric control

D Matt, J Harrowfield - ChemCatChem, 2021 - Wiley Online Library
Tertiary phosphines and other P (III)‐derivatives are the par excellence ligands in
industrially relevant homogeneous catalysis. A promising, recent development in this field …

Water-soluble phosphane-substituted cyclodextrin as an effective bifunctional additive in hydroformylation of higher olefins

J Leblond, J Potier, S Menuel, H Bricout… - Catalysis Science & …, 2017 - pubs.rsc.org
In cyclodextrin (CD)-mediated aqueous biphasic catalysis, favoring contacts between the
CD (“host”), the organic substrate (“guest”) and the water-soluble catalyst is crucial for the …

Cyclodextrin and phosphorus (III): A versatile combination for coordination chemistry and catalysis

M Jouffroy, D Armspach, D Matt - Dalton Transactions, 2015 - pubs.rsc.org
With the advent of efficient methods for functionalising cyclodextrins, the synthesis of a
variety of cyclodextrin-based P (III) ligands has been made possible. Capable of acting both …