The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

The addition of an allylic organometallic compound to a carbonyl compound or an imine is of
great synthetic interest because in this reaction together with a new functionality (hydroxyl or …

The addition of an organometallic reagent to a carbonyl compound or an imine represents
an important process in synthetic organic chemistry because in this reaction, together with a …

Organolithium reagents were first prepared in 1917 by Schlenk 1a and developed in the
following three decades by major contributions from Ziegler (who first prepared n-BuLi and …

Chiral tertiary alcohols and R-tertiary amines are important building blocks of naturally
occurring and artificial biologically active molecules. Although there are catalytic asymmetric …

Rapid and efficient access to structurally diverse β-fluoroalkylamines is in high demand, with
their wide presence and great importance in medicinal chemistry and drug development …

During the last century, organometallic reagents prepared from main group metals, 1 such
as organolithium, organomagnesium, and organozinc compounds, have played a central …

Enantioselective allylation is a highly used organic reaction to prepare chiral homoallylic
alcohols and amines, which serve as important building blocks in the synthesis of a variety …

The catalytic asymmetric addition reactions of organometallic reagents to CdN double bonds
of imines are fundamentally important processes, which provide convenient and versatile …

A Cu‐catalyzed diastereo‐and enantioselective borylative coupling reaction of 1, 3‐dienes
with imines was realized. Branched homoallylic amines are readily prepared in a syn …