Concepts relevant for the kinetic analysis of reversible reaction systems

NK Razdan, TC Lin, A Bhan - Chemical Reviews, 2023 - ACS Publications
The net rate of a reversible chemical reaction is the difference between unidirectional rates
of traversal along forward and reverse reaction paths. In a multistep reaction sequence, the …

Advances in the catalytic reductive amination of furfural to furfural amine: The momentous role of active metal sites

MK Saini, S Kumar, H Li, SA Babu… - …, 2022 - Wiley Online Library
One‐pot synthesis of sustainable primary amines by catalytic reductive amination of bio‐
based carbonyl compounds with NH3 and H2 is emerging as a promising and robust …

Rational design of selective metal catalysts for alcohol amination with ammonia

T Wang, J Ibañez, K Wang, L Fang, M Sabbe… - Nature Catalysis, 2019 - nature.com
The lack of selectivity for the direct amination of alcohols with ammonia (a modern and clean
route for the synthesis of primary amines) is an unsolved problem. Here, we combine first …

Efficient Synthesis of Pharmaceutical Intermediates from Biomass-Derived Aldehydes and Ketones over Robust NixAl Nanocatalysts

J Zhang, J Yang, X Li, H Liu, A Wang… - ACS Sustainable …, 2022 - ACS Publications
Heterogeneous catalytic reductive amination of biomass-based carbonyl compounds is a
highly attractive strategy to realize green and sustainable amine synthesis under mild …

Structure-sensitive and insensitive reactions in alcohol amination over nonsupported Ru nanoparticles

G Liang, Y Zhou, J Zhao, AY Khodakov… - ACS …, 2018 - ACS Publications
The reaction rates and selectivity of many metal-catalyzed reactions depend on the size of
the metal particles in the nanoscale range. Primary amines are important platform molecules …

Propanol amination over supported nickel catalysts: reaction mechanism and role of the support

CR Ho, V Defalque, S Zheng, AT Bell - ACS Catalysis, 2019 - ACS Publications
Ni-supported hydroxyapatite catalyst (Ni/HAP) was characterized and evaluated for
propanol amination to propylamine at 423 K. The reaction proceeds via dehydroamination, a …

Microwave-assisted reductive amination with aqueous ammonia: sustainable pathway using recyclable magnetic nickel-based nanocatalyst

M Manzoli, EC Gaudino, G Cravotto… - ACS Sustainable …, 2019 - ACS Publications
The development of sustainable protocols for the reductive amination is a highly desirable
pursuit in the domain of green synthesis. Magnetic nanocatalysts have found a unique niche …

Earth‐abundant metal‐catalyzed reductive amination: recent advances and prospect for future catalysis

J Liu, Y Song, L Ma - Chemistry–An Asian Journal, 2021 - Wiley Online Library
Nitrogen‐containing compounds, as an important class of chemicals, have been used
widely in pharmaceuticals, materials synthesis. Transition metal‐catalyzed reductive …

Reductive amination of 5‐hydroxymethylfurfural to 2, 5‐bis (aminomethyl) furan over alumina‐supported Ni‐based catalytic systems

Z Wei, Y Cheng, H Huang, Z Ma, K Zhou… - ChemSusChem, 2022 - Wiley Online Library
Mono‐and bimetallic Ni‐based catalysts were prepared by screening 6 supports and 14
secondary metals for reductive amination of 5‐hydroxymethylfurfural (5‐HMF) into 2, 5‐bis …

Switchable synthesis of furfurylamine and tetrahydrofurfurylamine from furfuryl alcohol over RANEY® nickel

Y Liu, K Zhou, H Shu, H Liu, J Lou, D Guo… - Catalysis Science & …, 2017 - pubs.rsc.org
RANEY® Ni proved to be an effective heterogeneous catalyst for switchable reductive
amination of furfuryl alcohol to tetrahydrofurfurylamine and furfurylamine with NH3 by simply …