“Turning over” definitions in catalytic cycles

S Kozuch, JML Martin - Acs Catalysis, 2012 - ACS Publications
“Indeed, the catalytic activity, for a valid comparison, must be referred to the number of
exposed surface atoms of a specified kind. Thus a convenient way to express catalytic …

TAP-2: An interrogative kinetics approach

JT Gleaves, GS Yablonskii, P Phanawadee… - Applied Catalysis A …, 1997 - Elsevier
The TAP-2 reactor system and the theoretical basis of TAP pulse response experiments are
discussed. On the basis of the TAP system, an alternative to the traditional kinetic approach …

[图书][B] Heterogeneous catalysis

GK Boreskov - 2003 - books.google.com
Georgii Konstantinovich Boreskov (1907-1984) was an eminent Russian scientist and
chemical engineer and a specialist in the field of catalysis. This book presents a translation …

Dynamic and static limitation in multiscale reaction networks, revisited

AN Gorban, O Radulescu - Advances in Chemical Engineering, 2008 - Elsevier
The concept of the limiting step gives the limit simplification: the whole network behaves as a
single step. This is the most popular approach for model simplification in chemical kinetics …

Unsteady-state operation of reactors with fixed catalyst beds

AN Zagoruiko, L Bobrova, N Vernikovskaya… - Reviews in Chemical …, 2021 - degruyter.com
The review is dedicated to the research and development work made in USSR and Russia
in the area of catalytic processes with artificially created unsteady-state conditions. The …

Entropy: the Markov ordering approach

AN Gorban, PA Gorban, G Judge - Entropy, 2010 - mdpi.com
The focus of this article is on entropy and Markov processes. We study the properties of
functionals which are invariant with respect to monotonic transformations and analyze two …

The michaelis-menten-stueckelberg theorem

AN Gorban, M Shahzad - Entropy, 2011 - mdpi.com
We study chemical reactions with complex mechanisms under two assumptions:(i)
intermediates are present in small amounts (this is the quasi-steady-state hypothesis or …

Voting and catalytic processes with inhomogeneities

M Mobilia, IT Georgiev - Physical Review E—Statistical, Nonlinear, and Soft …, 2005 - APS
We consider the dynamics of the voter model and of the monomer-monomer catalytic
process in the presence of many “competing” inhomogeneities and show, through exact …

Uncertainty quantification, propagation and characterization by Bayesian analysis combined with global sensitivity analysis applied to dynamical intracellular pathway …

O Eriksson, A Jauhiainen, S Maad Sasane… - …, 2019 - academic.oup.com
Motivation Dynamical models describing intracellular phenomena are increasing in size and
complexity as more information is obtained from experiments. These models are often over …

Mathematical modeling of oscillating CO oxidation on Pt-group metals at near atmospheric pressure: Activity of metallic and oxidized surfaces

AG Makeev, MM Slinko, D Luss - Applied Catalysis A: General, 2019 - Elsevier
This article is a theoretical and numerical analysis of experimental results concerning the
oscillatory and steady-state behavior during CO oxidation on Pd (100) and Pt (110) catalysts …