Endohedral metallofullerene molecular nanomagnets

Z Hu, S Yang - Chemical Society Reviews, 2024 - pubs.rsc.org
Magnetic lanthanide (Ln) metal complexes exhibiting magnetic bistability can behave as
molecular nanomagnets, also known as single-molecule magnets (SMMs), suitable for …

Magnetic properties of atomic clusters and endohedral metallofullerenes

J Zhao, X Huang, P Jin, Z Chen - Coordination Chemistry Reviews, 2015 - Elsevier
Magnetic clusters are aggregates of a few to thousands of atoms or molecules that exhibit
magnetism. Understanding the evolution of magnetism from individual atom to bulk solid is …

Enhancing T1 magnetic resonance imaging contrast with internalized gadolinium(III) in a multilayer nanoparticle

VS Marangoni, O Neumann… - Proceedings of the …, 2017 - National Acad Sciences
Multifunctional nanoparticles for biomedical applications have shown extraordinary potential
as contrast agents in various bioimaging modalities, near-IR photothermal therapy, and for …

Selective arc-discharge synthesis of Dy 2 S-clusterfullerenes and their isomer-dependent single molecule magnetism

CH Chen, DS Krylov, SM Avdoshenko, F Liu… - Chemical …, 2017 - pubs.rsc.org
A method for the selective synthesis of sulfide clusterfullerenes Dy2S@ C2n is developed.
Addition of methane to the reactive atmosphere reduces the formation of empty fullerenes in …

Magnetization relaxation in the single-ion magnet DySc 2 N@ C 80: quantum tunneling, magnetic dilution, and unconventional temperature dependence

DS Krylov, F Liu, A Brandenburg, L Spree… - Physical Chemistry …, 2018 - pubs.rsc.org
Relaxation of magnetization in endohedral metallofullerenes DySc2N@ C80 is studied at
different temperatures, in different magnetic fields, and in different molecular arrangements …

Effect of defects and oxygen vacancies on the RTFM properties of pure and Gd-doped CeO2 nanomaterials through soft XAS

S Soni, M Dave, B Dalela, PA Alvi, S Kumar… - Applied Physics A, 2020 - Springer
This work primarily is an investigation of the electronic structure properties of pure CeO 2
and Ce _ 1-x Gd _ x O _ 2 Ce 1-x Gd x O 2 (x= 0.02, 0.04, 0.06, 0.08 and 0.10) Nanoparticles …

Using internal strain and mass to modulate Dy⋯ Dy coupling and relaxation of magnetization in heterobimetallic metallofullerenes DyM 2 N@ C 80 and Dy 2 MN@ C …

Y Hao, G Velkos, S Schiemenz… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Endohedral clusters inside metallofullerenes experience considerable inner strain when the
size of the hosting cage is comparably small. This strain can be tuned in mixed-metal …

Single‐Molecule Magnets DyM2N@C80 and Dy2MN@C80 (M=Sc, Lu): The Impact of Diamagnetic Metals on Dy3+ Magnetic Anisotropy, Dy⋅⋅⋅Dy Coupling …

L Spree, C Schlesier, A Kostanyan… - … A European Journal, 2020 - Wiley Online Library
The substitution of scandium in fullerene single‐molecule magnets (SMMs) DySc2N@ C80
and Dy2ScN@ C80 by lutetium has been studied to explore the influence of the diamagnetic …

Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc 2 N@ C 80-I h with M running through the whole 4f row

Y Zhang, D Krylov, M Rosenkranz, S Schiemenz… - Chemical …, 2015 - pubs.rsc.org
Paramagnetic and variable temperature 13C and 45Sc nuclear magnetic resonance studies
are performed for nitride clusterfullerenes MSc2N@ C80 with icosahedral Ih (7) carbon …

Carbide clusterfullerene DyYTiC@ C 80 featuring three different metals in the endohedral cluster and its single-ion magnetism

A Brandenburg, DS Krylov, A Beger… - Chemical …, 2018 - pubs.rsc.org
Carbide clusterfullerene DyYTiC@ C80-Ih with three different metal atoms in the endohedral
cluster is obtained by arc-discharge synthesis with methane as reactive gas and is …