Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …

Low-valent early transition metals are often intrinsically highly reactive as a result of their
strong propensity toward oxidation to more stable high-valent states. Harnessing these …

First-row transition-metal-mediated reactions constitute an important and growing area of
research due to the low cost, low toxicity, and exceptional synthetic versatility of these …

The use of bis (pinacolato) diboron as the terminal reductant allows the efficient Ni-catalyzed
coupling of unactivated secondary and primary alkyl halides, generating the C (sp3)–C (sp3) …

The construction of C–C bonds by coupling reactions is an important process in synthetic
chemistry though expensive catalysts are required. Heterogeneous photocatalysis offers a …

In recent years solid evidence of HAT reactions involving water as hydrogen atom source
have been presented. In this work we demonstrate that the efficiency of titanocene (III) aqua …

The phenanthroindolizidine and phenanthroquinolizidine alkaloids, typified by tylophorine
and cryptopleurine, are a family of plant-derived small molecules with significant therapeutic …

In the last two decades, titanocene monochloride has been postulated as a monoelectronic
transfer reagent capable of catalyzing an important variety of chemical transformations. In …

The development of Green Chemistry inevitably involves the development of green
reagents. In this review, we highlight that Cp2TiCl is a reagent widely used in radical and …

Organophosphorus compounds (OPCs) have wide application in organic synthesis, material
sciences, and drug discovery. Generally, the vast majority of phosphorus atoms in OPCs are …