From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Polymers for electronics and spintronics

P Bujak, I Kulszewicz-Bajer, M Zagorska… - Chemical Society …, 2013 - pubs.rsc.org
This critical review is devoted to semiconducting and high spin polymers which are of great
scientific interest in view of further development of the organic electronics and the emerging …

Synthesis and Thin Films of Thermally Robust Quartet (S = 3/2) Ground State Triradical

C Shu, M Pink, T Junghoefer, E Nadler… - Journal of the …, 2021 - ACS Publications
High-spin (S= 3/2) organic triradicals may offer enhanced properties with respect to several
emerging technologies, but those synthesized to date typically exhibit small doublet quartet …

From high‐spin organic molecules to organic polymers with magnetic ordering

A Rajca - Chemistry–A European Journal, 2002 - Wiley Online Library
This concept paper outlines the design of the first π‐conjugated organic polymer with
magnetic ordering. This rational,“bottom‐up” macromolecular design is based on synthesis …

High-Spin Cation Radicals of MetaPara Aniline Oligomers

MM Wienk, RAJ Janssen - Journal of the American Chemical …, 1997 - ACS Publications
A series of linear and branched high-spin di-and tri (cation radical) s (1 2• 2+, 7 2• 2+, 3 3•
3+, 4 3• 3+, and 9 3• 3+) has been prepared by oxidation of the corresponding meta− para …

The physical organic chemistry of very high-spin polyradicals

A Rajca - Advances in Physical Organic Chemistry, 2005 - Elsevier
The physical organic chemistry of very high-spin polyradicals - ScienceDirect Skip to main
contentSkip to article Elsevier logo Journals & Books Search RegisterSign in View PDF …

[(Cp*)(dppe)Fe(III)−]+ Units Bridged through 1,3-Diethynylbenzene and 1,3,5-Triethynylbenzene Spacers: Ferromagnetic Metal−Metal Exchange Interaction

T Weyland, K Costuas, A Mari, JF Halet… - Organometallics, 1998 - ACS Publications
The bi-and trinuclear iron (III) complexes [1, 3-{Cp*(dppe) Fe (C⋮ C−)} 2 (C6H4)][PF6] 2 (2
2+) and [1, 3, 5-{Cp*(dppe) Fe (C⋮ C−)} 3 (C6H3)][PF6](3 3+) were prepared by oxidation of …

Recent advances in the syntheses of radical‐containing macromolecules

AJ Wingate, BW Boudouris - Journal of Polymer Science Part A …, 2016 - Wiley Online Library
Tailor‐made polymers containing specific chemical functionalities have ushered in a
number of emerging fields in polymer science. In most of these next‐generation applications …

Density functional study of intramolecular ferromagnetic interaction through m-phenylene coupling unit (I): UBLYP, UB3LYP, and UHF calculations

M Mitani, H Mori, Y Takano, D Yamaki… - The Journal of …, 2000 - pubs.aip.org
Polyradicals comprised of m-phenylene-bridged organic radicals are well known as building
blocks of organic ferromagnets, in which radical groups are connected with each other at the …

Organic Spin Clusters:  Macrocyclic-Macrocyclic Polyarylmethyl Polyradicals with Very High Spin S = 5−13

A Rajca, J Wongsriratanakul… - journal of the american …, 2004 - ACS Publications
Synthesis and magnetic studies of a new class of organic spin clusters, possessing
alternating connectivity of unequal spins, are described. Polyarylmethyl polyether precursors …