Hydroxide complexes of the late transition metals: Organometallic chemistry and catalysis
Transition metal hydroxides of the late transition metals are now relatively common, and play
a special role in both the synthesis of new complexes and in important catalytic reactions …
a special role in both the synthesis of new complexes and in important catalytic reactions …
Efficient ruthenium-catalyzed N-methylation of amines using methanol
TT Dang, B Ramalingam, AM Seayad - ACS Catalysis, 2015 - ACS Publications
An in situ-generated complex from [RuCp* Cl2] 2 and dpePhos ligand is reported as an
efficient catalyst in the presence of 5 mol% of LiOtBu for the N-methylation of amines using …
efficient catalyst in the presence of 5 mol% of LiOtBu for the N-methylation of amines using …
Easy α-alkylation of ketones with alcohols through a hydrogen autotransfer process catalyzed by RuCl2 (DMSO) 4
R Martínez, DJ Ramón, M Yus - Tetrahedron, 2006 - Elsevier
The electrophilic α-alkylation of ketones with alcohols is accomplished by a hydrogen
autotransfer process catalyzed by RuCl2 (DMSO) 4. The reaction can produce either simple …
autotransfer process catalyzed by RuCl2 (DMSO) 4. The reaction can produce either simple …
Homogeneous catalysis by organometallic polynuclear clusters
Homogeneous polynuclear metal clusters constitute a broad class of coordination
compounds with important applications in catalysis. The current interest of synthetic …
compounds with important applications in catalysis. The current interest of synthetic …
RuCl2 (DMSO) 4 catalyzes the β-alkylation of secondary alcohols with primary alcohols through a hydrogen autotransfer process
R Martínez, DJ Ramón, M Yus - Tetrahedron, 2006 - Elsevier
The electrophilic β-alkylation of secondary alcohols with primary alcohols is accomplished
by a hydrogen autotransfer process catalyzed by RuCl2 (DMSO) 4. The reaction can …
by a hydrogen autotransfer process catalyzed by RuCl2 (DMSO) 4. The reaction can …
Iron‐catalyzed Oppenauer‐type oxidation of alcohols
MG Coleman, AN Brown, BA Bolton… - Advanced Synthesis & …, 2010 - Wiley Online Library
A (hydroxycyclopentadienyl) iron dicarbonyl hydride catalyzes the Oppenauer‐type
oxidation of alcohols with acetone as the hydrogen acceptor. Many functional groups are …
oxidation of alcohols with acetone as the hydrogen acceptor. Many functional groups are …
Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation
CK Hill, JF Hartwig - Nature chemistry, 2017 - nature.com
Polyoxygenated hydrocarbons that bear one or more hydroxyl groups comprise a large set
of natural and synthetic compounds, often with potent biological activity. In synthetic …
of natural and synthetic compounds, often with potent biological activity. In synthetic …
Benzimidazolin-2-ylidene N-heterocyclic carbene complexes of ruthenium as a simple catalyst for the N-alkylation of amines using alcohols and diols
SP Shan, X Xiaoke, B Gnanaprakasam, TT Dang… - RSC …, 2015 - pubs.rsc.org
Simple air and moisture stable ruthenium complexes 1–3 and 3a were synthesized from
readily available benzannulated N-heterocyclic carbene ligands (bimy= benzimidazolin-2 …
readily available benzannulated N-heterocyclic carbene ligands (bimy= benzimidazolin-2 …
Efficient Dehydrogenation of Amines and Carbonyl Compounds Catalyzed by a Tetranuclear Ruthenium-μ-oxo-μ-hydroxo-hydride Complex
CS Yi, DW Lee - Organometallics, 2009 - ACS Publications
The tetranuclear ruthenium-μ-oxo-μ-hydroxo-hydride complex {[(PCy3)(CO) RuH] 4 (μ4-
O)(μ3-OH)(μ2-OH)}(1) was found to be a highly effective catalyst for the transfer …
O)(μ3-OH)(μ2-OH)}(1) was found to be a highly effective catalyst for the transfer …
Highly efficient abnormal NHC ruthenium catalyst for oppenauer-type oxidation and transfer hydrogenation reactions
L Pardatscher, BJ Hofmann, PJ Fischer… - ACS …, 2019 - ACS Publications
The ruthenium complex [Ru (OAc)(a-PC) 2] Br (3) containing two abnormal NHC ligands is
obtained by reaction of Ru (OAc) 2 (PPh3) 2 (1) with 1-(2-diphenylphosphinoethyl)-3 …
obtained by reaction of Ru (OAc) 2 (PPh3) 2 (1) with 1-(2-diphenylphosphinoethyl)-3 …