Transition-metal-catalyzed, coordination-assisted C (sp3)–H functionalization has
revolutionized synthetic planning over the past few decades as the use of these directing …

During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

Metalla‐electrocatalyzed C− H oxygenation represents one of the most straightforward and
sustainable approaches to access valuable oxygenated molecules. Despite the significant …

This Review summarizes the advancements in Pd-catalyzed C (sp3)–H activation via
various redox manifolds, including Pd (0)/Pd (II), Pd (II)/Pd (IV), and Pd (II)/Pd (0). While few …

Conspectus Directing group (DG) assistance provides a good solution to the problems of
reactivity and selectivity, two of the fundamental challenges in C (sp3)–H activation …

Computational studies on carboxylate-assisted C–H activation and functionalization at
group 8–10 transition metal centers are reviewed. This Review is organized by metal and …

Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

C H bonds are ubiquitous in organic compounds. It would, therefore, appear that direct
functionalization of substrates by activation of C H bonds would eliminate the multiple …

Palladium-catalyzed C H activation/C O bond-forming reactions have emerged as
attractive tools for organic synthesis. Typically, these reactions require strong chemical …