Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview of commonly employed DFT methods …

T Sperger, IA Sanhueza, I Kalvet… - Chemical …, 2015 - ACS Publications
The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

The Stille reaction, 38 years later

C Cordovilla, C Bartolomé, JM Martinez-Ilarduya… - Acs …, 2015 - ACS Publications
The first now-named Stille reaction was published 38 years ago, and the last comprehensive
revision of this catalysis was in 2004. Since then, the knowledge of the different steps of the …

Inorganometallics (transition metal–metalloid complexes) and catalysis

B Marciniec, C Pietraszuk, P Pawluc… - Chemical …, 2021 - ACS Publications
While the formation and breaking of transition metal (TM)–carbon bonds plays a pivotal role
in the catalysis of organic compounds, the reactivity of inorganometallic species, that is …

Glycosyl Cross-Coupling of Anomeric Nucleophiles: Scope, Mechanism, and Applications in the Synthesis of Aryl C-Glycosides

F Zhu, J Rodriguez, T Yang, I Kevlishvili… - Journal of the …, 2017 - ACS Publications
Stereoselective manipulations at the C1 anomeric position of saccharides are one of the
central goals of preparative carbohydrate chemistry. Historically, the majority of reactions …

Mechanistic Insights into the copper-cocatalyzed Sonogashira cross-coupling reaction: key role of an anion

X Wang, Y Song, J Qu, Y Luo - Organometallics, 2017 - ACS Publications
The Sonogashira cross-coupling reaction is one of the most important and widely used sp2–
sp carbon–carbon bond formation reactions in organic synthesis. Up to now, the exact …

Stille polycondensation: a multifaceted approach towards the synthesis of polymers with semiconducting properties

Z Liang, A Neshchadin, Z Zhang, FG Zhao, X Liu… - Polymer …, 2023 - pubs.rsc.org
Recent years have witnessed the rapid development of numerous organic polymer-based
semiconductors for applications in areas ranging from organic electronics to bioimaging and …

A short synthesis of delavatine a unveils new insights into site-selective cross-coupling of 3, 5-dibromo-2-pyrone

V Palani, CL Hugelshofer, I Kevlishvili… - Journal of the …, 2019 - ACS Publications
The recognition of latent symmetry in delavatine A has enabled a short synthesis of the
natural product starting from 3, 5-dibromo-2-pyrone. The concise synthetic route features a …

Mechanistic insights of Sn-based non-chemically-amplified resists under EUV irradiation

GK Belmonte, SW Cendron, PG Reddy… - Applied Surface …, 2020 - Elsevier
Formulating high sensitivity and resolution in Extreme Ultraviolet (EUV) resists is a serious
concern regarding the adaptation of EUV lithography. The incorporation of a high optical …

Recent advances in transition-metal-catalyzed (Csp2)-X (X= Se, Te, As, Sb) bond formation

L Rout, P Behera, T Punniyamurthy - Molecular Catalysis, 2024 - Elsevier
Aryl selenium, tellurium, arsenic and antimony compounds represent the privileged
structural scaffolds in synthetic chemistry for the construction of complex molecules from …

Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands

PM Uberman, SE Martín - Current Organic Chemistry, 2018 - benthamdirect.com
In the synthesis of new ligands for metal-catalyzed reactions, arsines are attracting particular
attention, because arsine ligands have been shown to be better ligands than structurally …