Advances and challenges in laminar flame experiments and implications for combustion chemistry
The state of the art and the further challenges of combustion chemistry research in laminar
flames are reviewed. Laminar flames constitute an essential part of kinetic model …
flames are reviewed. Laminar flames constitute an essential part of kinetic model …
Kinetics of elementary reactions in low-temperature autoignition chemistry
Advanced low-temperature combustion concepts that rely on compression ignition have
placed new technological demands on the modeling of low-temperature oxidation in general …
placed new technological demands on the modeling of low-temperature oxidation in general …
Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2
Ozonolysis is a major tropospheric removal mechanism for unsaturated hydrocarbons and
proceeds via “Criegee intermediates”—carbonyl oxides—that play a key role in tropospheric …
proceeds via “Criegee intermediates”—carbonyl oxides—that play a key role in tropospheric …
Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO
Although carbonyl oxides,“Criegee intermediates,” have long been implicated in
tropospheric oxidation, there have been few direct measurements of their kinetics, and only …
tropospheric oxidation, there have been few direct measurements of their kinetics, and only …
Combustion chemistry probed by synchrotron VUV photoionization mass spectrometry
F Qi - Proceedings of the Combustion Institute, 2013 - Elsevier
Combustion is directly related to energy conversion and the environment. Gas-phase
chemical reactions such as thermal decomposition, oxidation and recombination play a …
chemical reactions such as thermal decomposition, oxidation and recombination play a …
The physical chemistry of Criegee intermediates in the gas phase
DL Osborn, CA Taatjes - International Reviews in Physical …, 2015 - Taylor & Francis
Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …
Influence of functional groups on low-temperature combustion chemistry of biofuels
B Rotavera, CA Taatjes - Progress in Energy and Combustion Science, 2021 - Elsevier
Ongoing progress in synthetic biology, metabolic engineering, and catalysis continues to
produce a diverse array of advanced biofuels with complex molecular structure and …
produce a diverse array of advanced biofuels with complex molecular structure and …
Chemical kinetics of cyclic ethers in combustion
LS Tran, O Herbinet, HH Carstensen… - Progress in Energy and …, 2022 - Elsevier
Abstract Cyclic Ethers (CEs) belong to a class of compounds of importance to understand
the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of …
the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of …
Photoelectron photoion coincidence spectroscopy provides mechanistic insights in fuel synthesis and conversion
Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …
OH roaming and beyond in the unimolecular decay of the methyl-ethyl-substituted Criegee intermediate: observations and predictions
Alkene ozonolysis generates short-lived Criegee intermediates that are a significant source
of hydroxyl (OH) radicals. This study demonstrates that roaming of the separating OH …
of hydroxyl (OH) radicals. This study demonstrates that roaming of the separating OH …