Perfluoropyridine: discovery, chemistry, and applications in polymers and material science
R Gautam, I Geniza, ST Iacono, CM Friesen… - Molecules, 2022 - mdpi.com
Perfluoropyridine (PFPy) is an organofluorine compound that has been employed for a
variety of applications, from straightforward chemical synthesis to more advanced functions …
variety of applications, from straightforward chemical synthesis to more advanced functions …
[HTML][HTML] Synthesis of complex unnatural fluorine-containing amino acids
The area of fluorinated amino acid synthesis has seen rapid growth over the past decade.
As reports of singly fluorinated natural amino acid derivatives have grown, researchers have …
As reports of singly fluorinated natural amino acid derivatives have grown, researchers have …
Quantification of Phenolic Hydroxyl Groups in Lignin via 19F NMR Spectroscopy
Phenolic moieties strongly influence lignin reactivity and physical properties, and thus
accurate quantification of phenolic groups in lignin is a critical analytical chemistry need …
accurate quantification of phenolic groups in lignin is a critical analytical chemistry need …
Carboxylic acid deoxyfluorination and one-pot amide bond formation using pentafluoropyridine (PFP)
WDG Brittain, SL Cobb - Organic Letters, 2021 - ACS Publications
This work describes the application of pentafluoropyridine (PFP), a cheap commercially
available reagent, in the deoxyfluorination of carboxylic acids to acyl fluorides. The acyl …
available reagent, in the deoxyfluorination of carboxylic acids to acyl fluorides. The acyl …
One-pot ester and thioester formation mediated by pentafluoropyridine (PFP)
Acyl fluorides are valuable synthetic intermediates, but in some cases they can be
challenging to handle and difficult to isolate given their susceptibility to degradation. In …
challenging to handle and difficult to isolate given their susceptibility to degradation. In …
Total synthesis of the natural chalcone lophirone E, synthetic studies toward benzofuran and indole-based analogues, and investigation of anti-leishmanial activity
L Pozzetti, R Ibba, S Rossi, O Taglialatela-Scafati… - Molecules, 2022 - mdpi.com
The potential of natural and synthetic chalcones as therapeutic leads against different
pathological conditions has been investigated for several years, and this class of …
pathological conditions has been investigated for several years, and this class of …
Au (I) Catalyzed HF Transfer: Tandem Alkyne Hydrofluorination and Perfluoroarene Functionalization
D Mulryan, J Rodwell, NA Phillips, MR Crimmin - ACS catalysis, 2022 - ACS Publications
HF transfer reactions between organic substrates are potentially useful transformations.
Such reactions require the development of catalytic systems that can promote both …
Such reactions require the development of catalytic systems that can promote both …
Perfluoroaryl and perfluoroheteroaryl reagents as emerging new tools for peptide synthesis, modification and bioconjugation
WDG Brittain, CR Coxon - Chemistry–A European Journal, 2022 - Wiley Online Library
Peptides and proteins are becoming increasingly valuable as medicines, diagnostic agents
and as tools for biomedical sciences. Much of this has been underpinned by the emergence …
and as tools for biomedical sciences. Much of this has been underpinned by the emergence …
Shaken not stirred: perfluoropyridine-polyalkylether prepolymers
CM Friesen, AR Kelley, ST Iacono - Macromolecules, 2022 - ACS Publications
The purpose of this work was to employ perfluoropolyalkylethers (PFPAEs) with
perfluoropyridines (PFPs) to form telechelic oligomers for use in low-temperature materials …
perfluoropyridines (PFPs) to form telechelic oligomers for use in low-temperature materials …
Pentafluorobenzene: Promising Applications in Diagnostics and Therapeutics
Pentafluorobenzene (PFB) represents a class of aromatic fluorine compounds employed
exclusively across a spectrum of chemical and biological applications. PFBs are credited …
exclusively across a spectrum of chemical and biological applications. PFBs are credited …