Single-atom heterogeneous catalysts (SACs) incorporating isolated metal centers on solid
supports demonstrate promise for improving the sustainability of commercial organic …

High-throughput experimentation is a common practice in the optimization of chemical
synthesis. Chemists design reaction arrays to optimize the yield of couplings between …

Tuning the surface-embellishing ligands of metal nanoparticles (NPs) is a powerful strategy
to modulate their morphology and surface electronic and functional features, impacting their …

Complexes of palladium and nickel with N-heterocyclic carbene ligands (M/NHC, M= Pd, Ni)
are widely used as effective catalysts for various amination reactions. A previously …

Evidence of the involvement of a “cocktail”-type catalytic system in the alkyne and alkene
hydrosilylation reaction in the presence of platinum on a carbon support is reported. The …

The mercury drop test is a widely used method often regarded as decisive for discriminating
between homogeneous and heterogeneous catalysis in organometallic systems. However …

C-Amino-1, 2, 4-triazoles are challenging polynitrogen substrates for metal-catalyzed
arylation due to their multidentate character, enhanced coordinating ability and decreased …

The combination of metal‐based homogeneous and heterogeneous catalysts in the same
reaction media is a powerful, yet relatively unexplored approach in organic chemistry. This …

Ruthenium-catalyzed amination reactions have gained much attention in recent times. Due
to the low cost and versatile nature of ruthenium, its chemistry is expanding rapidly. The …

A family of well-defined Λ-and Δ-configured octahedral cationic chiral-at-cobalt catalysts
were expanded through a straightforward postcomplexation of the bromine-functionalized …