PolyHIPEs: Recent advances in emulsion-templated porous polymers

MS Silverstein - Progress in Polymer Science, 2014 - Elsevier
Porous polymers with well-defined porosities and high specific surface areas in the form of
monoliths, films, and beads are being used in a wide range of applications (reaction …

Nanosilica reinforced ion-exchange polyHIPE type membrane for removal of nickel ions: Preparation, characterization and adsorption studies

MR Moghbeli, A Khajeh, M Alikhani - Chemical Engineering Journal, 2017 - Elsevier
Abstract Highly porous styrene/2-ethylhexylacrylate/divinylbenzene polymerized high
internal phase emulsion (ST/2EHA/DVB polyHIPE) solid foams reinforced using various …

Polypyrrole@ polyHIPE composites for hexavalent chromium removal from water

ZA Chaleshtari, R Foudazi - ACS Applied Polymer Materials, 2020 - ACS Publications
In the present study, polymerized high internal phase emulsions, known as polyHIPEs, are
used as a template for the synthesis of polypyrrole (PPy) monolithic composites. The unique …

Influence of the macromolecular surfactant features and reactivity on morphology and surface properties of emulsion-templated porous polymers

K Mathieu, C Jérôme, A Debuigne - Macromolecules, 2015 - ACS Publications
This work investigates key parameters of a straightforward macromolecular surfactant-
assisted functionalization strategy of porous polymers produced by high internal phase …

A statistical approach for tailoring the morphological and mechanical properties of polystyrene PolyHIPEs: looking through experimental design

HH Mert, MS Mert, EH Mert - Materials Research Express, 2019 - iopscience.iop.org
The influence of experimental parameters on the morphological and mechanical properties
of hierarchical macroporous polymers prepared via emulsion templating was investigated by …

An advanced approach for the generation of complex cellular material representative volume elements using distance fields and level sets

B Sonon, B François, TJ Massart - Computational mechanics, 2015 - Springer
A general and widely tunable method for the generation of representative volume elements
for cellular materials based on distance and level set functions is presented. The approach …

Highly permeable macroporous polymers via controlled agitation of emulsion templates

M Tebboth, A Kogelbauer, A Bismarck - Chemical Engineering Science, 2015 - Elsevier
This work presents an investigation into how the pore diameter, pore throat diameter and
permeability of emulsion templated macroporous polymers (polyM/HIPE) can be controlled …

Engineering toolbox for systematic design of polyHIPE architecture

P Dhavalikar, J Shenoi, K Salhadar, M Chwatko… - Polymers, 2021 - mdpi.com
Polymerization of high internal phase emulsions (polyHIPEs) is a well-established method
for the production of high porosity foams. Researchers are often regulated to using a time …

Liquid–liquid extraction within emulsion Templated macroporous polymers

M Tebboth, A Kogelbauer… - Industrial & Engineering …, 2015 - ACS Publications
Macroporous polymerized high internal phase emulsion (polyHIPE) flow cells were
manufactured and used to extract caffeine from an aqueous solution using ethyl acetate …

Simultaneous synthesis and chemical functionalization of emulsion-templated porous polymers using nitroxide-terminated macromolecular surfactants

K Mathieu, J De Winter, C Jérôme, A Debuigne - Polymer Chemistry, 2017 - pubs.rsc.org
The design of functional 3D macroporous monoliths has become a necessity for a wide
range of applications. The traditional post-modification strategies of porous materials are …