Recent advances in the synthesis and reactivity of azetidines: strain-driven character of the four-membered heterocycle
H Mughal, M Szostak - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Azetidines represent one of the most important four-membered heterocycles used in organic
synthesis and medicinal chemistry. The reactivity of azetidines is driven by a considerable …
synthesis and medicinal chemistry. The reactivity of azetidines is driven by a considerable …
Review of Polyethylenimine through Ring-Opening Polymerization Reactions and Its Application in CO2 Capture
AA Al-Absi, AE Ogungbenro, AM Benneker… - Journal of …, 2024 - Elsevier
Despite numerous challenges and a variety of ring-opening polymerization techniques
employed, polyethylenimine (PEI), whether in branched or linear forms with various …
employed, polyethylenimine (PEI), whether in branched or linear forms with various …
Spontaneous alternating copolymerization of aziridines with tosyl isocyanate toward polyureas
H Huang, H Wei, L Huang, T Fan, X Li, Z Zhang… - European Polymer …, 2023 - Elsevier
We report a new synthetic approach toward cyclic polyureas through alternating
copolymerization of aziridines with tosyl isocyanate. Aziridines (ethyleneimine, and (S)-2 …
copolymerization of aziridines with tosyl isocyanate. Aziridines (ethyleneimine, and (S)-2 …
Polymerizations of 2-(Trimethylsilyl) ethanesulfonyl-activated aziridines
A novel N-sulfonyl aziridine, N-((2-(trimethylsilyl) ethyl) sulfonyl)-2-methyl-aziridine (SES-
MeAz) was synthesized, and its controlled anionic ring-opening polymerization to form poly …
MeAz) was synthesized, and its controlled anionic ring-opening polymerization to form poly …
Anionic Ring-Opening Polymerizations of N-Sulfonylaziridines in Ionic Liquids
The anionic ring-opening polymerization (AROP) of sulfonylaziridines in ionic liquids (ILs) is
reported. In imidazolium ILs, the polymerization of 2-methyl-N-tosylaziridine (TsMAz) is not …
reported. In imidazolium ILs, the polymerization of 2-methyl-N-tosylaziridine (TsMAz) is not …
Ultrafast organocatalytic ring‐opening polymerization of N‐sulfonyl aziridine in the melt
R Chen, Y Wang, L Zhu, Z Zhang - Journal of Polymer Science, 2021 - Wiley Online Library
An ultrafast approach for controlled synthesis of well‐defined polysulfonamides is
established through organocatalytic anionic ring‐opening polymerization (ROP) of N …
established through organocatalytic anionic ring‐opening polymerization (ROP) of N …
Azetidine synthesis by La(OTf)3-catalyzed intramolecular regioselective aminolysis of cis-3,4-epoxy amines
Y Kuriyama, Y Sasano, Y Iwabuchi - Frontiers in Chemistry, 2023 - frontiersin.org
Azetidine is a prevalent structural motif found in various biologically active compounds. In
this research paper, we report La (OTf) 3-catalyzed intramolecular regioselective aminolysis …
this research paper, we report La (OTf) 3-catalyzed intramolecular regioselective aminolysis …
Tetrabutylammonium fluoride initiated anionic ring-opening polymerizations of N–sulfonyl aziridines
H Wang, J Li, Z Li, B Liu, K Chen, Z Zhang, Y Hu… - European Polymer …, 2020 - Elsevier
Ionic pair tetrabutylammonium halide (TBAX) was efficient initiator in anionic ring-opening
polymerizations (AROPs) of N-sulfonyl aziridines, in which the tetrabutylammonium fluoride …
polymerizations (AROPs) of N-sulfonyl aziridines, in which the tetrabutylammonium fluoride …
Activated Monomer Polymerization of an N-Sulfonylazetidine
Previously, N-(methanesulfonyl) azetidine (MsAzet) was found to polymerize anionically via
ring-opening at temperatures> 100° C to form p (MsAzet) in the presence of an anionic …
ring-opening at temperatures> 100° C to form p (MsAzet) in the presence of an anionic …
The Anionic Polymerization of a tert-Butyl-Carboxylate-Activated Aziridine
N-Sulfonyl-activated aziridines are known to undergo anionic-ring-opening polymerizations
(AROP) to form polysulfonyllaziridines. However, the post-polymerization deprotection of the …
(AROP) to form polysulfonyllaziridines. However, the post-polymerization deprotection of the …